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  • In crystallo homolytic cleavage of a terminal lanthanum( iii )–methyl bond by Cu Kα X-radiation forms a La( ii ) complex
Title: In crystallo homolytic cleavage of a terminal lanthanum( iii )–methyl bond by Cu Kα X-radiation forms a La( ii ) complex
A new La(ii) synthesis involves SCXRD experiments on the La(iii) methyl complex La(SAriPr6)2CH3, AriPr6= C6H3-2,6-(C6H2-2,4,6-iPr3)2, with Cu Kα X-rays that results in homolytic La-CH3cleavage and formation of the La(ii) complex La(SAriPr6)2.  more » « less
Award ID(s):
2452677
PAR ID:
10677816
Author(s) / Creator(s):
 ;  ;  ;  
Publisher / Repository:
Royal Society of Chemistry
Date Published:
Journal Name:
Chemical Communications
Volume:
62
Issue:
2
ISSN:
1359-7345
Page Range / eLocation ID:
547 to 550
Subject(s) / Keyword(s):
lanthanum, methyl cleavage, in crystallo, X-ray, organometallic, rare-earth metal
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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