S. D. von Fellenberg et al. reported the first mid-infrared detection of a flare from Sgr A*. The JWST/MIRI/Medium Resolution Spectrometer observations were consistent with an orbiting hotspot undergoing electron injection with a spectrum that subsequently breaks from synchrotron cooling. However, mid-infrared extinction measurements appropriate for these data were not yet determined, and, therefore, the temporal evolution of the absolute spectral index remained unknown. This work applies new Sgr A* extinction measurements to the flare observations. The evolution of the spectral index after the peak is fully consistent with that reported in Paper I with a maximum absolute mid-infrared spectral indexα_MIR= 0.45 ± 0.01_stat± 0.08_sysduring the second mid-infrared flare peak, matching the known near-infrared spectral index during bright states (α_NIR≈ 0.5). There was a near-instantaneous change in the mid-infrared spectral index of Δα_MIR= 0.33 ± 0.06_stat± 0.11_sysat the flare onset. We propose this as a quantitative definition for this infrared flare’s beginning, physically interpreted as the underlying electron distribution’s transition into a hard power-law distribution. This paper also reports the Submillimeter Array millimeter polarization during the flare, which shows a small, distorted, but overall CW-oriented StokesQ–Uloop during the third mid-infrared peak. Extrapolating the mid-infrared flux power law to the millimeter yields a variable flux consistent with the observed 220 GHz emission. These results, together with the Paper I modeling, plausibly suggest a single hotspot produced both the mid-infrared and millimeter variability during this event. However, additional flares are required to make a general statement about the millimeter and mid-infrared connection.