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Title: Temperature-dependent polarized Raman scattering in candidate topological superconductor 2M-WS 2
Abstract The monoclinic 2M phase of tungsten disulfide (2M-WS2) has emerged as a promising platform for topological superconductivity, combining topological surface states, anisotropic thermoelectric response, and superconductivity with a critical temperature of ∼8.8K. A detailed understanding of its electron–phonon coupling and phonon anharmonicity is, however, still lacking. Here, we investigate the phonon properties of few-layer 2M-WS2as functions of laser power, temperature, polarization, and magnetic field using polarized Raman spectroscopy down to 12.5 K. We uncover an unusual, non-linear temperature dependence of the Raman shifts in selected modes, consistent with strong, mode-dependent electron–phonon interactions that dominate over phonon–phonon scattering at low temperatures. Angle-resolved polarized Raman measurements further reveal a pronounced change in the polarization behavior of the A g (4) mode at ∼316cm−1upon cooling, indicating a modification of the underlying lattice and electronic anisotropy. In contrast, the applied magnetic field has a negligible influence on the Raman response over the measured temperature range. Together, these results advance the microscopic understanding of vibrational dynamics and electron–phonon coupling in few-layer 2M-WS2and provide important insight into the lattice-electronic interplay relevant for its unconventional superconductivity and potential quantum and thermoelectric device applications.  more » « less
Award ID(s):
2300640 2104036
PAR ID:
10683630
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
IOP Science
Date Published:
Journal Name:
2D Materials
Volume:
13
Issue:
2
ISSN:
2053-1583
Page Range / eLocation ID:
025009
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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