More Like this

1. Soybean growth and production as affected by struvite as a phosphorus source in eastern Arkansas

   https://doi.org/10.1002/csc2.20852  

   Omidire, Niyi S.; Brye, Kristofor R.; English, Leah; Kekedy‐Nagy, Laszlo; Greenlee, Lauren; Popp, Jennie; Roberts, Trenton L. (January 2023, Crop Science)

   Abstract Struvite (MgNH₄PO₄·6H₂O) has been precipitated from liquid waste streams to recover valuable nutrients, such as phosphorus (P) and nitrogen (N), that can be used as an alternative fertilizer‐P source. Because prior research has focused on greenhouse studies, it is necessary to expand struvite evaluations to the field‐scale to include row‐crop responses. The objective of this field study was to evaluate the effects of two struvite materials (electrochemically precipitated struvite, ECST; and chemically precipitated struvite, CPST) relative to other common fertilizer‐P sources (diammonium phosphate, DAP; triple superphosphate, TSP; rock phosphate, RP; and monoammonium phosphate, MAP) on soybean [Glycine max(L.) Merr.] response and economics in two consecutive growing seasons in a P‐deficient, silt‐loam soil (Aquic Fraglossudalfs) in eastern Arkansas. Averaged across years, soybean aboveground tissue P uptake was largest (P < .05) from ECST (28.4 kg ha⁻¹), which was similar to CPST (26.7 kg ha⁻¹) and TSP (25.9 kg ha⁻¹) and was smallest from RP (21.4 kg ha⁻¹). In 2019, seed yield was largest (P < .05) from ECST (4.1 Mg ha⁻¹), which was similar to DAP, CPST, RP, TSP, and MAP, and was smallest from the unamended control (3.6 Mg ha⁻¹). In 2020, seed yield was numerically greatest from CPST (2.8 Mg ha⁻¹) and was numerically smallest from ECST (2.2 Mg ha⁻¹). Results showed that wastewater‐recovered struvite materials have the potential to be a viable, alternative fertilizer‐P source for soybean production in a P‐deficient, silt‐loam soil, but further work is needed to confirm struvite's cost effectiveness. 

   more » « less
2. C(sp ³ )–H oxidation and chlorination catalysed by a bioinspired pincer iron( iii ) complex

   https://doi.org/10.1039/D2DT02005J  

   Han, Jian; Tan, Liming; Wan, Yanjun; Li, Gang; Anderson, Stephen N. (August 2022, Dalton Transactions)

   A pincer iron(iii) catalyst for the oxidation and chlorination of C(sp³)–H bonds was developed. 

   more » « less
3. SN 2021wuf: A transitional type Ia supernova with a low-velocity gradient

   https://doi.org/10.1051/0004-6361/202451048  

   Zeng, Xiangyun; Li, Sai; Wang, Xiaofeng; Zheng, Sheng; Andrew_Howell, D; Azaleee_Bostroem, K; McCully, Curtis; Esamdin, Ali; Liu, Jialian; Iskandar, Abdusamatjan; et al (November 2024, Astronomy & Astrophysics)

   In this paper, we present an extensive analysis of SN 2021 wuf, a transition between Ia-norm and SN 1991T-like supernovae, which exploded at the periphery of the tidal bridge between the pair galaxy NGC 6500 and NGC 6501, at a redshift ofz = 0.01. Our observations, ranging from −21 to +276 days relative to theB-band maximum light, reveal that SN 2021wuf exhibits properties akin to normal SNe Ia, with a peak absolute magnitude ofM_max(B)  ∼   − 19.49  ±  0.10 mag and a post-peak decline rate of Δm₁₅(B)  ∼  1.11  ±  0.06 mag. The peak bolometric luminosity of this SN is estimated as 1.58  × 10⁴³erg s⁻¹, corresponding to a⁵⁶Ni mass ofM_Ni  ∼  0.64  ±  0.05 M_⊙. The spectral features, including high-velocity Si IIλ6355 lines, a plateau in the Si IIλ6355 velocity evolution and the nickel-to-iron ratio in the nebular phase, suggest a potential pulsating delayed detonation mechanism. The absence of intermediate-mass elements in the early phase and the high photospheric temperature, as inferred from the line-strength ratio of Si IIλ5972 to Si IIλ6355 (named asR(Si II)), further support this classification. 

   more » « less
4. Transition metal-doped MgO nanoparticles for nutrient recycling: an alternate Mg source for struvite synthesis from wastewater

   https://doi.org/10.1039/D0EN00660B  

   Silva, Manoj; Murzin, Vadim; Zhang, Lihua; Baltrus, John; Baltrusaitis, Jonas (November 2020, Environmental Science: Nano)

   null (Ed.)

   Nutrient nitrogen (N) and phosphorus (P) recovery from wastewater is an important challenge for enhanced environmental sustainability. Herein we report the synthesis and properties of mesoporous MgO nanoparticles doped with copper (Cu), iron (Fe), and zinc (Zn) as an alternative low-solubility high-abundance magnesium (Mg) source for crystalline struvite precipitation from nutrient-laden wastewater. Undoped MgO was shown to have the fastest phosphate (PO 4 3− ) adsorption kinetics with a k 2 value of 0.9 g g −1 min −1 at room temperature. The corresponding rate constant decreased for Cu–MgO (0.175 g g −1 min −1 ), Zn–MgO (0.145 g g −1 min −1 ), and Fe–MgO (0.02 g g −1 min −1 ). Undoped MgO resulted in the highest PO 4 3− removal at 94%, while Cu–MgO, Fe–MgO, and Zn–MgO resulted in 90%, 66% and 66%, respectively, under equivalent reaction conditions. All dopants resulted in the production of struvite as the main product with the incorporation of the transition metals into the struvite crystal lattice. X-ray absorption spectroscopy (XAS) showed that the majority of the Cu, Fe, and Zn were primarily in the +2, +3, and +2 oxidation states, respectively. XAS also showed that the Cu atoms exist in elongated octahedral coordination, while Fe was shown to be in octahedral coordination. Zn was shown to be in a complex disordered environment with octahedral sites coexisting with the majority of the tetrahedral sites. Finally, X-ray photoelectron spectroscopy data suggest a two-fold struvite surface enrichment with dopant metals, with Cu exhibiting an interesting new local binding structure. The dopant concentrations utilized were consistent with those found in natural Mg minerals, suggesting that (a) utilizing natural mineral periclase as the Mg source for struvite production can result in struvite formation, albeit at the expense of the reaction kinetics and overall yields, while also (b) supplying essential micronutrients, such as Zn and Cu, necessary for balanced nutrient uptake. 

   more » « less
5. Assessment of Struvite as an Alternative Sources of Fertilizer-Phosphorus for Flood-Irrigated Rice

   https://doi.org/10.3390/su14159621  

   Brye, Kristofor R.; Omidire, Niyi S.; English, Leah; Parajuli, Ranjan; Kekedy-Nagy, Laszlo; Sultana, Ruhi; Popp, Jennie; Thoma, Greg; Roberts, Trenton L.; Greenlee, Lauren F. (August 2022, Sustainability)

   Phosphorus (P) recovery from wastewaters as struvite (MgNH4PO4·6H2O) may be a viable alternative fertilizer-P source for agriculture. The objective of this study was to evaluate the economic and environmental implications of struvite as a fertilizer-P source for flood-irrigated rice (Oryza sativa) relative to other commonly used commercially available fertilizer-P sources. A field study was conducted in 2019 and 2020 to evaluate the effects of wastewater-recovered struvite (chemically precipitated struvite (CPST) and electrochemically precipitated struvite (ECST)) on rice yield response in a P-deficient, silt–loam soil in eastern Arkansas relative to triple superphosphate, monoammonium and diammonium phosphate, and rock phosphate. A life cycle assessment methodology was used to estimate the global warming potentials associated with rice produced with the various fertilizer-P sources. Life cycle inventory data were based on the field trials conducted with and without struvite application for both years. A partial budget analysis showed that, across both years, net revenues for ECST and CPST were 1.4 to 26.8% lower than those associated with the other fertilizer-P sources. The estimated greenhouse gas emissions varied between 0.58 and 0.70 kg CO2 eq kg rice−1 from CPST and between 0.56 and 0.81 kg CO2 eq kg rice−1 from ECST in 2019 and 2020, respectively, which were numerically similar to those for the other fertilizer-P sources in 2019 and 2020. The similar rice responses compared to commercially available fertilizer-P sources suggest that wastewater-recovered struvite materials might be an alternative fertilizer-P-source option for flood-irrigated rice production if struvite can become price-competitive to other fertilizer-P sources. 

   more » « less