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This report is on the nature of strain in thin films of yttrium iron garnet (YIG) on yttrium aluminum garnet (YAG) substrates due to film-substrate lattice mismatch and the resulting induced magnetic anisotropy. Films with thickness 55 nm to 380 nm were deposited on (100), (110), and (111) YAG substrates using pulsed laser deposition (PLD) techniques and characterized by structural and magnetic characterization techniques. The in-plane strain determined to be compressive using X-ray diffraction (XRD). It varied from −0.12% to −0.98% and increased in magnitude with increasing film thickness and was relatively large in films on (100) YAG. The out-of-plane strain was tensile and also increased with increasing film thickness. The estimated strain-induced magnetic anisotropy field, found from XRD data, was out of plane; its value increased with film thickness and ranged from 0.47 kOe to 3.96 kOe. Ferromagnetic resonance (FMR) measurements at 5 to 21 GHz also revealed the presence of a perpendicular magnetic anisotropy that decreased with increasing film thickness and its values were smaller than values obtained from XRD data. The PLD YIG films on YAG substrates exhibiting a perpendicular anisotropy field have the potential for use in self-biased sensors and high-frequency devices.
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This content will become publicly available on November 1, 2026
Seed-Layer-Assisted Liquid-Phase Epitaxial Growth of YIG Films on Single-Crystal Yttrium Aluminum Garnet Substrates: Evidence for Enhancement in Strain-Induced Anisotropy
Epitaxial thick films of yttrium iron garnet (YIG) are ideal for use in microwave devices due to their low losses at high frequencies. This report is on the growth of strain-engineered YIG films by liquid-phase epitaxy (LPE) on yttrium aluminum garnet (YAG) substrates with −3% lattice mismatch with YIG. Since the use of a lattice-matched substrate is preferred for LPE growths, a seed layer of YIG, 370–400 nm in thickness, was deposited by pulsed laser deposition (PLD) on (100), (110), and (111) YAG substrates. The seed layers were stoichiometric with magnetic parameters in agreement with the parameters for bulk single-crystal YIG and with strain-induced perpendicular magnetic anisotropy field Ha = 0.19–0.43 kOe. YIG films, 4 to 8.4 μm in thickness, were grown by LPE at 870 °C on YAG substrates with the seed layers using the PbO+B2O3 flux and annealed in air at 1000 °C. The films were Y-rich and Fe-deficient and confirmed to be epitaxial single crystals by X-ray diffraction. The saturation magnetization 4πMs at room temperature was rather high and ranged from 1.9 kG to 2.3 kG. Ferromagnetic resonance at 5–15 GHz showed the absence of significant magneto-crystalline anisotropy in the LPE films with the line-width ΔH in the range 85–160 Oe, and Ha = 0.27–0.80 kOe which is much higher than for the seed layers. The high magnetization and Ha-values for the LPE films could be partially attributed to the off-stoichiometry. Although the strain due to the film–substrate lattice mismatch contributes to Ha, the mismatch in the thermal expansion coefficients for YIG and YAG is also a likely cause of Ha due to the high growth and annealing temperatures. The LPE-grown YIG films with high strain-induced anisotropy fields have the potential for use in self-biased microwave devices.
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- PAR ID:
- 10696043
- Publisher / Repository:
- MDPI
- Date Published:
- Journal Name:
- Crystals
- Volume:
- 15
- Issue:
- 11
- ISSN:
- 2073-4352
- Page Range / eLocation ID:
- 953
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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