Abstract The dielectric gap between the scanning probe microscopy (SPM) tip and the surface of a ferroelectric using conductive atomic force microscopy and piezoresponse force microscopy (PFM) is investigated. While the gap functions as a dielectric layer, it also allows tunneling current to inject charges into the ferroelectric when a critical loading force between 10–20 µN is applied to a tip with a radius of 25 nm under a bias voltage of 0.5 V. It is observed that the permittivity of the dielectric gap determines the coercive voltage measured by the piezoresponse hysteresis loop. While such studies done in air often produce coercive voltages much larger than those studied for the same materials in capacitor‐based studies, the use of high permittivity media such as water (ɛr= 79) or silicone oil (ɛr= 2.1‐2.8) produces coercive fields that more closely match those measured in conventional capacitor‐based polarization hysteresis loop measurements. Furthermore, using water as a dielectric medium in PFM imaging enhances the accuracy in extracting the amplitude and phase data from periodically poled lithium niobate crystals. These findings provide insight into the nanoscale phenomena of polarization switching instigated by the SPM tip and provide a pathway to improved quantitative studies.
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This content will become publicly available on July 25, 2027
Sub‐Nanometer Curvature Unlocks Quantum Orbital Flexoelectricity in Graphene
ABSTRACT Flexoelectricity, defined as polarization induced by strain gradients, is especially pronounced in two‐dimensional (2D) materials due to their mechanical flexibility and sensitivity to deformation. In nanostructures with nanometer‐scale curvature, bending can perturb out‐of‐plane π orbitals and generate quantum‐mechanical polarization and electrostatic modulation beyond classical lattice distortion alone. Here, we combine scanning probe measurements and first‐principles calculations to provide experimental and theoretical evidence for large intrinsic quantum orbital flexoelectricity in graphene nanowrinkles (GNWrs) with estimated polarization densities of Pth∼ 4 C m−2and Pexp∼ 1 C m−2, exceeding those of mesoscale systems by 5 to 7 orders of magnitude. These GNWrs exhibit high apex curvature, undergo atomic‐level buckling, and produce localized strain fields, as supported by atomic force microscopy analysis and Raman spectroscopy. Kelvin probe force microscopy reveals curvature‐dependent work‐function shifts, while conductive atomic force microscopy detects reproducible GNWr‐associated currents with a threshold voltage (Φth∼ 1 V) comparable to the band offset predicted by ab initio calculations (∼ 1.2 V). These results support an interpretation in which curvature‐induced flexoelectric dipoles reshape the local electronic potential. GNWrs therefore provide a structurally simple carbon‐based platform for probing quantum‐mechanical flexoelectricity.
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- PAR ID:
- 10700674
- Publisher / Repository:
- Wiley
- Date Published:
- Journal Name:
- Advanced Materials
- ISSN:
- 0935-9648
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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