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1. Shock compression experiments using the DiPOLE 100-X laser on the high energy density instrument at the European x-ray free electron laser: Quantitative structural analysis of liquid Sn

   https://doi.org/10.1063/5.0201702  

   Gorman, M G; McGonegle, D; Smith, R F; Singh, S; Jenkins, T; McWilliams, R S; Albertazzi, B; Ali, S J; Antonelli, L; Armstrong, M R; et al (April 2024, Journal of Applied Physics)

   X-ray free electron laser (XFEL) sources coupled to high-power laser systems offer an avenue to study the structural dynamics of materials at extreme pressures and temperatures. The recent commissioning of the DiPOLE 100-X laser on the high energy density (HED) instrument at the European XFEL represents the state-of-the-art in combining x-ray diffraction with laser compression, allowing for compressed materials to be probed in unprecedented detail. Here, we report quantitative structural measurements of molten Sn compressed to 85(5) GPa and ∼3500 K. The capabilities of the HED instrument enable liquid density measurements with an uncertainty of ∼1% at conditions which are extremely challenging to reach via static compression methods. We discuss best practices for conducting liquid diffraction dynamic compression experiments and the necessary intensity corrections which allow for accurate quantitative analysis. We also provide a polyimide ablation pressure vs input laser energy for the DiPOLE 100-X drive laser which will serve future users of the HED instrument. 

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2. Identification of carbon dioxide in an exoplanet atmosphere

   https://doi.org/10.1038/s41586-022-05269-w  

   Ahrer, Eva-Maria; Alderson, Lili; Batalha, Natalie M; Batalha, Natasha E; Bean, Jacob L; Beatty, Thomas G; Bell, Taylor J; Benneke, Björn; Berta-Thompson, Zachory K; Carter, Aarynn L; et al (February 2023, Nature)

   Abstract Carbon dioxide (CO₂) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO₂is an indicator of the metal enrichment (that is, elements heavier than helium, also called ‘metallicity’)^1–3, and thus the formation processes of the primary atmospheres of hot gas giants^4–6. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets^7–9. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO₂, but have not yielded definitive detections owing to the lack of unambiguous spectroscopic identification^10–12. Here we present the detection of CO₂in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science programme^13,14. The data used in this study span 3.0–5.5 micrometres in wavelength and show a prominent CO₂absorption feature at 4.3 micrometres (26-sigma significance). The overall spectrum is well matched by one-dimensional, ten-times solar metallicity models that assume radiative–convective–thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide and hydrogen sulfide in addition to CO₂, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 micrometres that is not reproduced by these models. 

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3. Iron Bonding with Light Elements: Implications for Planetary Cores Beyond the Binary System

   https://doi.org/10.3390/cryst14121016  

   Yang, Hong; Wang, Wenzhong; Mao, Wendy L (December 2024, Crystals)

   Light element alloying in iron is required to explain density deficit and seismic wave velocities in Earth’s core. However, the light element composition of the Earth’s core seems hard to constrain as nearly all light element alloying would reduce the density and sound velocity (elastic moduli). The alloying light elements include oxidizing elements like oxygen and sulfur and reducing elements like hydrogen and carbon, yet their chemical effects in the alloy system are less discussed. Moreover, Fe-X-ray Absorption Near Edge Structure (Fe-XANES) fingerprints have been studied for silicate materials with ferrous and ferric ions, while not many X-ray absorption spectroscopy (XAS) studies have focused on iron alloys, especially at high pressures. To investigate the bonding nature of iron alloys in planetary interiors, we presented X-ray absorption spectroscopy of iron–nitrogen and iron–carbon alloys at high pressures up to 50 GPa. Together with existing literature on iron–carbon, –hydrogen alloys, we analyzed their edge positions and found no significant difference in the degree of oxidation among these alloys. Pressure effects on edge positions were also found negligible. Our theoretical simulation of the valence state of iron, alloyed with S, C, O, N, and P also showed nearly unchanged behavior under pressures up to 300 GPa. This finding indicates that the high pressure bonding of iron alloyed with light elements closely resembles bonding at the ambient conditions. We suggest that the chemical properties of light elements constrain which ones can coexist within iron alloys. 

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4. Laboratory Study of the Cameron Bands, the First Negative Bands, and Fourth Positive Bands in the Middle Ultraviolet 180–280 nm by Electron Impact Upon CO

   https://doi.org/10.1029/2020JE006602  

   Lee, Rena A.; Ajello, Joseph M.; Malone, Charles P.; Evans, J. Scott; Veibell, Victoir; Holsclaw, Gregory M.; McClintock, William E.; Hoskins, Alan C.; Jain, Sonal; Gérard, Jean‐Claude; et al (January 2021, Journal of Geophysical Research: Planets)

   Abstract We have analyzed medium‐resolution (full width at half maximum, FWHM = 1.2 nm), Middle UltraViolet (MUV; 180–280 nm) laboratory emission spectra of carbon monoxide (CO) excited by electron impact at 15, 20, 40, 50, and 100 eV under single‐scattering conditions at 300 K. The MUV emission spectra at 100 eV contain the Cameron Bands (CB) CO(a³Π → X¹Σ⁺), the fourth positive group (4PG) CO(A¹Π → X¹Σ⁺), and the first negative group (1NG) CO⁺(B²Σ⁺→ X²Σ) from direct excitation and cascading‐induced emission of an optically thin CO gas. We have determined vibrational intensities and emission cross sections for these systems, important for modeling UV observations of the atmospheres of Mars and Venus. We have also measured the CB “glow” profile about the electron beam of the long‐lived CO (a³Π) state and determined its average metastable lifetime of 3 ± 1 ms. Optically allowed cascading from a host of triplet states has been found to be the dominant excitation process contributing to the CB emission cross section at 15 eV, most strongly by the d³Δ and a'³Σ⁺electronic states. We normalized the CB emission cross section at 15 eV electron impact energy by multilinear regression (MLR) analysis to the blended 15 eV MUV spectrum over the spectral range of 180–280 nm, based on the 4PG emission cross section at 15 eV that we have previously measured (Ajello et al., 2019,https://doi.org/10.1029/2018ja026308). We find the CB total emission cross section at 15 eV to be 7.7 × 10⁻¹⁷ cm². 

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5. A Multiwavelength View of the Nearby Calcium-strong Transient SN 2025coe in the X-Ray, Near-infrared, and Radio Wavebands

   https://doi.org/10.3847/1538-4357/ae707e  

   Kumar, Sahana; Baer-Way, Raphael; Ravi, Aravind P; Modjaz, Maryam; Chandra, Poonam; Valenti, Stefano; Kwok, Lindsey A; Tinyanont, Samaporn; Foley, Ryan J; Howell, D Andrew; et al (June 2026, The Astrophysical Journal)

   Abstract Calcium-strong transients (CaSTs) are a subclass of faint and rapidly evolving supernovae (SNe) that exhibit strong calcium features and notably weak oxygen features. The small but growing population of CaSTs exhibits some aspects similar to thermonuclear SNe but others similar to massive star core-collapse events, leading to intriguing questions on their physical origins. SN 2025coe is one of the nearest CaSTs discovered to date, and our coordinated multiwavelength observations obtained days to weeks postexplosion reveal new insights into these enigmatic transients. With the most robust near-IR (NIR) spectroscopic time series of a CaST collected to date, SN 2025coe shows spectral signatures characteristic of Type Ib SNe (SNe Ib; i.e., He-rich stripped-envelope SNe (SESNe)). SN 2025coe is the third X-ray-detected CaST and our analysis of Neil Gehrels Swift Observatory X-ray data suggests interaction with 0.12 ± 0.11M_⊙of circumstellar material (CSM) extending to at least 2 × 10¹⁵cm (∼30,000R_⊙), while our analysis of the 1–240 GHz radio nondetections gives an outer radius of that CSM of at most ∼5 × 10¹⁵cm. This inferred nearby high-density CSM extending out to (3.5 ± 1.5) × 10¹⁵cm is similar to that seen in the other two X-ray-detected CaSTs, and its presence suggests that either intensive mass loss from a massive star or some exotic pre-SN mass ejection may be a common feature of this subclass. Our work also expands upon recent studies of the optical properties of SN 2025coe and explores our current understanding of different progenitor systems that could possibly produce CaSTs. 

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