Measurements of the production of ultralong-range Rydberg dimers through photoassocation in an ultracold atomic gas are reported. The molecular potential associated with the Rydberg state is anisotropic and the molecular states are characterized by the vibrational quantum number and the total angular momentum , where and are the electronic orbital angular momentum and rotational angular momentum, respectively. The measured molecular binding energies agree reasonably well with theoretical predictions. Additionally, the electron-atom scattering leads to broader line shapes in the photoassociation spectrum than might be expected simply from the angular momentum of the initial colliding cold-atom pairs.
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This content will become publicly available on August 1, 2027
Effect of an applied magnetic field on Sr84 n1D2 ultralong-range Rydberg dimers
Photoassociation of ultralong-range Rydberg dimers from an ultracold atomic gas in a magnetic field is studied. In the absence of magnetic fields, the electronic wave function is aligned along the rotating molecular axis through electron-atom scattering. With increasing magnetic field strength, the symmetry axis of the electron wave function becomes determined by the applied field. While the ground-state atom has no spin or net charge to interact directly with the magnetic field, the dimer wave function in the limit of strong magnetic field becomes aligned along the applied field. Photoassociation spectra show that with increasing field, an increasing number of rovibrational states are excited, indicating strong coupling between rotational states within the Rydberg dimer.
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- Award ID(s):
- 2409598
- PAR ID:
- 10706708
- Publisher / Repository:
- American Physical Society
- Date Published:
- Journal Name:
- Physical Review A
- Volume:
- 114
- Issue:
- 2
- ISSN:
- 2469-9926
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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