%AMcConnell, Cameron [Department of Chemistry Boston College 2609 Beacon St. 02467‐3860 Chestnut Hill Massachusetts USA]%AMcConnell, Cameron [Department of Chemistry; Boston College; 2609 Beacon St. 02467-3860 Chestnut Hill Massachusetts USA]%ACampbell, Patrick [Department of Chemistry and Biochemistry 1253 University of Oregon 97403‐1253 Eugene Oregon USA]%ACampbell, Patrick [Department of Chemistry and Biochemistry; 1253 University of Oregon; 97403-1253 Eugene Oregon USA]%AFristoe, Carey [Department of Chemistry and Biochemistry 1253 University of Oregon 97403‐1253 Eugene Oregon USA]%AFristoe, Carey [Department of Chemistry and Biochemistry; 1253 University of Oregon; 97403-1253 Eugene Oregon USA]%AMemmel, Philipp [Department of Chemistry Boston College 2609 Beacon St. 02467‐3860 Chestnut Hill Massachusetts USA]%AMemmel, Philipp [Department of Chemistry; Boston College; 2609 Beacon St. 02467-3860 Chestnut Hill Massachusetts USA]%AZakharov, Lev [Department of Chemistry and Biochemistry 1253 University of Oregon 97403‐1253 Eugene Oregon USA]%AZakharov, Lev [Department of Chemistry and Biochemistry; 1253 University of Oregon; 97403-1253 Eugene Oregon USA]%ALi, Bo [Department of Chemistry; Boston College; 2609 Beacon St. 02467-3860 Chestnut Hill Massachusetts USA]%ALi, Bo [Department of Chemistry Boston College 2609 Beacon St. 02467‐3860 Chestnut Hill Massachusetts USA]%ADarrigan, Clovis [Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Matériaux; UMR CNRS 5254; Université de Pau et des Pays de l'Adour; Avenue de l'Universite 64000 Pau France]%ADarrigan, Clovis [Institut des Sciences Analytiques et de Physico‐Chimie pour l'Environnement et les Matériaux UMR CNRS 5254 Université de Pau et des Pays de l'Adour Avenue de l'Universite 64000 Pau France]%AChrostowska, Anna [Institut des Sciences Analytiques et de Physico‐Chimie pour l'Environnement et les Matériaux UMR CNRS 5254 Université de Pau et des Pays de l'Adour Avenue de l'Universite 64000 Pau France]%AChrostowska, Anna [Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Matériaux; UMR CNRS 5254; Université de Pau et des Pays de l'Adour; Avenue de l'Universite 64000 Pau France]%ALiu, Shih‐Yuan [Department of Chemistry Boston College 2609 Beacon St. 02467‐3860 Chestnut Hill Massachusetts USA]%ALiu, Shih-Yuan [Department of Chemistry; Boston College; 2609 Beacon St. 02467-3860 Chestnut Hill Massachusetts USA]%BJournal Name: European Journal of Inorganic Chemistry; Journal Volume: 2017; Journal Issue: 15; Related Information: CHORUS Timestamp: 2023-10-06 13:55:29 %D2017%IWiley Blackwell (John Wiley & Sons) %JJournal Name: European Journal of Inorganic Chemistry; Journal Volume: 2017; Journal Issue: 15; Related Information: CHORUS Timestamp: 2023-10-06 13:55:29 %K %MOSTI ID: 10035121 %PMedium: X; Size: p. 2207-2210 %TSynthesis and Characterization of 1,2‐Azaborine‐Containing Phosphine Ligands: A Comparative Electronic Structure Analysis %X

The synthesis and characterization of two 1,2‐azaborine‐containing phosphine ligands are described. The structural and electronic parameters of the two ligands were compared with those of their direct all‐carbon analogues using X‐ray crystallography and UV‐photoelectron and IR spectroscopy. Our results indicate that the azaborine‐containing ligands are significantly stronger electron donors than their corresponding carbonaceous counterparts, while the steric parameters remain similar.

%0Journal Article