%AHartmann, Nathaniel [Department of Chemistry and Biochemistry; University of California; Santa Barbara; 93106 USA]%AWu, Guang [Department of Chemistry and Biochemistry; University of California; Santa Barbara; 93106 USA]%AHayton, Trevor [Department of Chemistry and Biochemistry; University of California; Santa Barbara; 93106 USA]%BJournal Name: Chemical Science; Journal Volume: 9; Journal Issue: 31 %D2018%IRoyal Society of Chemistry (RSC) %JJournal Name: Chemical Science; Journal Volume: 9; Journal Issue: 31 %K %MOSTI ID: 10064254 %PMedium: X %TSynthesis and reactivity of a nickel( ii ) thioperoxide complex: demonstration of sulfide-mediated N 2 O reduction %X

The “masked” terminal nickel sulfide [K(18-crown-6)][LtBuNiII(S)] mediates the reduction of N2O by CO,viathe thioperoxide complex [K(18-crown-6)][LtBuNiII2-SO)].

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