%AShogren, Arial%AZarnetske, Jay%AAbbott, Benjamin%ABratsman, Samuel%ABrown, Brian%ACarey, Michael%AFulweber, Randy%AGreaves, Heather%AHaines, Emma%AIannucci, Frances%AKoch, Joshua%AMedvedeff, Alexander%AO'Donnell, Jonathan%APatch, Leika%APoulin, Brett%AWilliamson, Tanner%ABowden, William%BJournal Name: Earth System Science Data; Journal Volume: 14; Journal Issue: 1 %D2022%I %JJournal Name: Earth System Science Data; Journal Volume: 14; Journal Issue: 1 %K %MOSTI ID: 10329273 %PMedium: X %TMulti-year, spatially extensive, watershed-scale synoptic stream chemistry and water quality conditions for six permafrost-underlain Arctic watersheds %XAbstract. Repeated sampling of spatially distributed riverchemistry can be used to assess the location, scale, and persistence ofcarbon and nutrient contributions to watershed exports. Here, we provide acomprehensive set of water chemistry measurements and ecohydrologicalmetrics describing the biogeochemical conditions of permafrost-affectedArctic watersheds. These data were collected in watershed-wide synopticcampaigns in six stream networks across northern Alaska. Three watershedsare associated with the Arctic Long-Term Ecological Research site at ToolikField Station (TFS), which were sampled seasonally each June and August from2016 to 2018. Three watersheds were associated with the National ParkService (NPS) of Alaska and the U.S. Geological Survey (USGS) and weresampled annually from 2015 to 2019. Extensive water chemistrycharacterization included carbon species, dissolved nutrients, and majorions. The objective of the sampling designs and data acquisition was tocharacterize terrestrial–aquatic linkages and processing of material instream networks. The data allow estimation of novel ecohydrological metricsthat describe the dominant location, scale, and overall persistence ofecosystem processes in continuous permafrost. These metrics are (1)subcatchment leverage, (2) variance collapse, and (3) spatial persistence.Raw data are available at the National Park Service Integrated Resource Management Applications portal (O'Donnell et al., 2021, https://doi.org/10.5066/P9SBK2DZ) and within the Environmental Data Initiative (Abbott, 2021, https://doi.org/10.6073/pasta/258a44fb9055163dd4dd4371b9dce945). %0Journal Article