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Creators/Authors contains: "Alexy, Eric J."

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  1. ; ; ; ; ; ; ( , Journal of the American Chemical Society)
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  2. ; ; ; ( , Advanced Synthesis & Catalysis)
    Abstract

    The enantioselective palladium‐catalyzed decarboxylative allylic alkylation of fully substituted α‐hydroxy acyclic enol carbonates providing tetrasubstituted benzoin derivatives is reported. Investigation into the transformation revealed that preparation of the starting material as a single enolate isomer is crucial for optimal enantioselectivity. The obtained alkylation products contain multiple reactive sites that can be utilized toward the synthesis of stereochemically rich derivatives.

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