Search for: All records

A survey of the lichens of Mount Mitchell State Park, North Carolina, published in 2017, recovered 171 species and reported 27 historically reported taxa missing. Here we report 72 lichen taxa as new for the park—based on both recent and historical specimens—for a total of 243 total taxa reported for all time points. In addition, 13 of the 27 taxa reported missing for the park in the 2017 survey were rediscovered. Most of these were found by either investigating non-spruce-fir substrates, which was the focus of the most recent survey in 2016, or returning to localities where historical specimens had previously been collected and intensively searching for the species. A revised list of 27 taxa that have not been seen since at least the early 1970s is presented, nine of which belong to the speciose genus Cladonia. The updated checklist for the park contains a surprisingly high level of cyanolichen diversity, suggesting the impacts of pollution and invasive insects on the lichen biota of the park are not as severe as previously thought. Molecular data (nrITS) confirm that Parmelia neodiscordans is distinct from other species of Parmelia and suggest that Appalachian material identified as P. omphalodes may be conspecific with the eastern Asian species P. ‘fertilis B’. Lastly, five rare lichens recorded from the park (Alectoria fallacina, Hypotrachyna densirhizinata, Lobarina scrobiculata, Nephroma parile and Parmelia neodiscordans) are proposed for conservation at the state level. 

The Hikurangi Margin (HM) is a subduction zone along the east coast of the North Island of New Zealand where varying instances of slow slip events (SSEs) and earthquakes occur. These SSEs occur at different time scales and depths when comparing the northern and southern ends of the margin. Previous studies show that the rock comprising the accretionary wedge of the northern margin have low permeabilities, which could induce overpressures and modulate the occurrence of SSEs. Permeability rises when an SSE fractures the rocks within the deep wedge promoting fluid flow and thus dissipating the overpressures along and above the décollement. As fractures heal and permeability recovers overpressures build up once again. Although this cycle may explain the occurrence of SSEs along northern Hikurangi, it is not yet clear how intrinsic permeability varies in rocks above the décollement elsewhere along the margin. To better understand the disparity in SSE occurrence, rock samples from the northern and central part of the margin have been tested for permeability and elastic properties. We tested samples from the Weber, Whangai, Dannevirke and Wanstead formations, which are representative of the lithologies above the décollement in the central margin, and range in age from the Cretaceous to the mid to late Paleogene. We found that the Weber (PQ) and Whangai (PO) formation samples from central HM have higher permeability than northern HM rocks from the same formation in the north. This study provides insight into the mechanisms that lead to significantly fewer SSEs along the central HM. In the near future, we plan to conduct a suite of physical experiments that will include permeability recovery after fracturing, compaction, and ultrasonic velocity analysis to help further understand the stark differences in slip behavior observed along the margin. 

Description of endMT abnormalities and abnormal response to flow in TS iPSC-ECs 

Abstract Climate‐driven warming is projected to intensify wildfires, increasing their frequency and severity globally. Wildfires are an increasingly significant source of atmospheric deposition, delivering nutrients, organic matter, and trace metals to coastal and open ocean waters. These inputs have the potential to fertilize or inhibit microbial growth, yet their ecological impacts remain poorly understood. This study examines how ash leachate, derived from the 2017 Thomas Fire in California and lab‐produced ash from Oregon vegetation, affects coastal plankton communities. Shipboard experiments off the California coast examined how pre‐existing plankton biomass concentrations mediate responses to ash leachates. We found that ash leachate contained dissolved organic matter (DOM) that significantly increased bacterioplankton specific growth rates and DOM remineralization rates but had a negligible effect on bacterioplankton growth efficiency, suggesting low DOM bioavailability. Furthermore, ash‐derived DOM had a higher potential to accumulate in high biomass water, where pre‐existing DOM substrates may better support bacterial metabolism. Ash leachate had a neutral to negative effect on phytoplankton division rates and decreased microzooplankton grazing rates, particularly in low biomass water, leading to increased phytoplankton accumulation. Nanoeukaryotes accumulated in low biomass water, whereas picoeukaryotes andSynechococcusaccumulated in high biomass water. Our findings suggest that the influence of ash deposition on DOM cycling, phytoplankton accumulation, and broader marine food web dynamics depends on pre‐existing biomass levels. Understanding these interactions is critical for predicting the biogeochemical consequences of increasing wildfire activity on marine ecosystems. 

Hybrid complexes incorporating synthetic Mn-porphyrins into an artificial four-helix bundle domain of bacterial reaction centers created a system to investigate new electron transfer pathways. The reactions were initiated by illumination of the bacterial reaction centers, whose primary photochemistry involves electron transfer from the bacteriochlorophyll dimer through a series of electron acceptors to the quinone electron acceptors. Porphyrins with diphenyl, dimesityl, or fluorinated substituents were synthesized containing either Mn or Zn. Electrochemical measurements revealed potentials for Mn(III)/Mn(II) transitions that are ~ 0.4 V higher for the fluorinated Mn-porphyrins than the diphenyl and dimesityl Mn-porphyrins. The synthetic porphyrins were introduced into the proteins by binding to a four-helix bundle domain that was genetically fused to the reaction center. Light excitation of the bacteriochlorophyll dimer of the reaction center resulted in new derivative signals, in the 400 to 450 nm region of light-minus-dark spectra, that are consistent with oxidation of the fluorinated Mn(II) porphyrins and reduction of the diphenyl and dimesityl Mn(III) porphyrins. These features recovered in the dark and were not observed in the Zn(II) porphyrins. The amplitudes of the signals were dependent upon the oxidation/reduction midpoint potentials of the bacteriochlorophyll dimer. These results are interpreted as photo-induced charge-separation processes resulting in redox changes of the Mn-porphyrins, demonstrating the utility of the hybrid artificial reaction center system to establish design guidelines for novel electron transfer reactions. 

Abstract Clinopyroxene is a rock-forming mineral that commonly hosts melt inclusions in mafic to intermediate composition volcanic and plutonic rocks. It is highly resistant to alteration compared to other co-existing phenocrysts such as plagioclase. Several recent studies have 40Ar/39Ar dated clinopyroxene in Neoproterozoic to Miocene basalts and dolerites. To assess the viability of the technique at the youngest end of the geologic time scale, we performed 40Ar/39Ar incremental heating experiments on clinopyroxene-hosted melt inclusions from a variety of mafic lithologies and tectonic settings. Most samples produced precise plateau ages including several Quaternary basalts to andesites as young as 0.6 Ma. All data are indistinguishable from new and/or published 40Ar/39Ar ages on groundmass or plagioclase from the same samples. The source of potassium (K) and resulting 40Ar* within clinopyroxene has been debated, but thus far has only been inferred based on 40Ar/39Ar data. Using electron probe microanalysis (EPMA) we show that there is negligible K in the clinopyroxene host, but substantial K (e.g., 1–4 wt%) in trapped melt inclusions and minor amounts in plagioclase inclusions. Thus, melt inclusions, which are common in phenocrysts in basaltic magmas, can be used to obtain accurate and precise 40Ar/39Ar ages for difficult-to-date volcanic and plutonic rocks from the Precambrian to the Pleistocene. 

The Pinaleño Mountains of southeastern Arizona is the eastern‐most metamorphic core complex in the southern U.S. and northern Mexican Cordillera. This study investigates the thermal history and exhumation record of the Pinaleño core complex using mica⁴⁰Ar/³⁹Ar, apatite and zircon (U‐Th)/He, and apatite fission‐track thermochronometers. The Pinaleño Mountains experienced two periods of rapid cooling during the Cenozoic. The first period, from ca. 27 to 21 Ma, records tectonic exhumation related to the development of the core complex and extensional shear zone. This period was followed by a relatively quiescent interval from 21 to 13.5 Ma that records little to no exhumation. The second period of rapid cooling, from 13.5 to 11 Ma, records tectonic exhumation related to high‐angle normal faulting, characteristic of the Basin and Range province. The exhumation timing of the Pinaleño core complex matches previously recognized spatiotemporal trends in the southern Basin and Range province and indicates that core complex exhumation in this region started in southeastern Arizona (ca. 32–33°N) and migrated both northward and southward. These trends correlate well with the latitude and timing of subduction of the Pacific‐Farallon spreading ridge and the migration of the Mendocino (northward) and Rivera (southward) triple junctions. Spatiotemporal core complex exhumation trends also correlate well with regional magmatism associated with the mid‐Cenozoic flare‐up, including syn‐extensional intrusive rocks found in the footwalls of core complexes. 

Bimetallic heterostructures, including core–shell and Janus configurations, often offer unique electrocatalytic properties compared to monometallic nanoparticles. However, achieving precise control over both elemental composition and spatial arrangement within these structures remains a challenge. Here, an electrosynthesis method is introduced that enables the fabrication of heterostructured bimetallic nanoparticles with precise, independent control of their elemental distribution. By leveraging dual‐channel scanning electrochemical cell microscopy (SECCM), the local ionic environment is dynamically modulated in situ, adjusting the deposition bias between channels to achieve selective electrodeposition. This approach allows temporal control over the solution conditions within the SECCM droplet, facilitating the synthesis of multi‐layer core–shell nanoparticles with tunable thickness, number, and sequence of layers. This technique is demonstrated with Pt–Cu and Pt–Ni systems, synthesizing arrays of Cu@Pt and Pt@Cu core–shell structures, which are then screened for catalytic activity in hydrogen evolution (HER) and oxygen reduction (ORR) reactions. The high spatial resolution and on‐demand control over the composition and structure make this method well‐suitable for creating arrays of complex, multi‐metallic heterostructures, which is expected to accelerate the discovery of advanced electrocatalytic materials, offering a platform for efficient and scalable electrocatalyst screening.