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Platinum Complexes from C–H Activation of Sterically Hindered [C^N] Donor Benzothiophene Imine Ligands: Synthesis and Photophysical Properties

https://doi.org/10.1021/acsomega.0c03993

Anderson, Craig M. ; Coffey, Belle ; Morales, Leslie ; Greenberg, Matthew W. ; Norman, Matthew ; Weinstein, Michael ; Brown, Garrett ; Tanski, Joseph M. ( October 2020 , ACS Omega)

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Stereoselective C-X and regioselective C-H activation to, and selective C(sp)-C(sp) reductive elimination from, platinum compounds with thiophene-derived ligands

https://doi.org/10.1016/j.tetlet.2019.151156

Anderson, Craig M. ; Brown, Garrett ; Greenberg, Matthew W. ; Yu, David ; Bowen, Nellie ; Ahmed, Rahma ; Yost-Bido, Melissa ; Wray, Alina ( October 2019 , Tetrahedron Letters)

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Synthesis, characterization, and photophysical properties of cyclometalated N-Heterocyclic carbene Platinum(II) complexes

https://doi.org/10.1016/j.jorganchem.2018.10.026

Mastrocinque, Francesco ; Anderson, Craig M. ; Elkafas, Adel M. ; Ballard, Isabel V. ; Tanski, Joseph M. ( February 2019 , Journal of Organometallic Chemistry)

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Synthesis, characterization, and photophysical properties of bismetalated platinum complexes with benzothiophene ligands

https://doi.org/10.1016/j.jorganchem.2018.12.010

Anderson, Craig M. ; Mastrocinque, Claudio ; Greenberg, Matthew W. ; McClellan, Ian C. ; Duman, Leila ; Oh, Nathaniel ; Mastrocinque, Francesco ; Pizzuto, Michael ; Tran, Kaylynn ; Tanski, Joseph M. ( March 2019 , Journal of Organometallic Chemistry)

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Photophysical Properties of Cyclometalated Platinum(II) Diphosphine Compounds in the Solid State and in PMMA Films

https://doi.org/10.1021/acsomega.1c04509

Coffey, Belle ; Clough, Lily ; Bartkus, Daphne D. ; McClellan, Ian C. ; Greenberg, Matthew W. ; LaFratta, Christopher N. ; Tanski, Joseph M. ; Anderson, Craig M. ( October 2021 , ACS Omega)

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A ruthenium–platinum metal complex that binds to sarcin ricin loop RNA and lowers mRNA expression

https://doi.org/10.1039/c8cc02131g

Jain, Swapan S. ; Anderson, Craig M. ; Sapse, Iden A. ; Lundgren, Silvie H. ; Freer, Abigail K. ; Hoang, Hang ; Jain, Kyan ; Breshears, Madeleine ( January 2018 , Chemical Communications)

IT127 is a dinuclear transition metal complex that contains a Pt( ii ) and a Ru( iii ) metal center. We have shown that IT127 is significantly more effective in binding the 29-base sarcin ricin loop (SRL) RNA in comparison to Cisplatin, a hallmark anticancer agent. Binding site analysis shows that IT127 prefers purine bases and the GAGA tetraloop region of SRL RNA. Our results with a dihydrofolate reductase (DHFR) model system reveal that IT127 binding to mRNA reduces translation of DHFR enzyme and that the Ru( iii ) and Pt( ii ) centers in IT127 appear to work in a synergistic manner.

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