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Abstract The enormous increase in mid-IR sensitivity and spatial and spectral resolution provided by the JWST spectrographs enables, for the first time, detailed extragalactic studies of molecular vibrational bands. This opens an entirely new window for the study of the molecular interstellar medium in luminous infrared galaxies (LIRGs). We present a detailed analysis of rovibrational bands of gas-phase CO, H₂O, C₂H₂, and HCN toward the heavily obscured eastern nucleus of the LIRG VV 114, as observed by NIRSpec and the medium resolution spectrograph on the Mid-InfraRed Instrument (MIRI MRS). Spectra extracted from apertures of 130 pc in radius show a clear dichotomy between the obscured active galactic nucleus (AGN) and two intense starburst regions. We detect the 2.3μm CO bandheads, characteristic of cool stellar atmospheres, in the star-forming regions, but not toward the AGN. Surprisingly, at 4.7μm, we find highly excited CO (T_ex≈ 700–800 K out to at least rotational levelJ= 27) toward the star-forming regions, but only cooler gas (T_ex≈ 200 K) toward the AGN. We conclude that only mid-infrared pumping through the rovibrational lines can account for the equilibrium conditions found for CO and H₂O in the deeply embedded starbursts. Here, the CO bands probe regions with an intense local radiation field inside dusty young massive star clusters or near the most massive young stars. The lack of high-excitation molecular gas toward the AGN is attributed to geometric dilution of the intense radiation from the bright point source. An overview of the relevant excitation and radiative transfer physics is provided in an appendix. 

Abstract We present an analysis of 10 ks snapshot Chandra observations of 12 shocked post-starburst galaxies, which provide a window into the unresolved question of active galactic nuclei (AGN) activity in post-starburst galaxies and its role in the transition of galaxies from active star formation to quiescence. While seven of the 12 galaxies have statistically significant detections (with two more marginal detections), the brightest only obtained 10 photons. Given the wide variety of hardness ratios in this sample, we chose to pursue a forward-modeling approach to constrain the intrinsic luminosity and obscuration of these galaxies, rather than stacking. We constrain the intrinsic luminosity of obscured power laws based on the total number of counts and spectral shape, itself mostly set by the obscuration, with hardness ratios consistent with the data. We also tested thermal models. While all the galaxies have power-law models consistent with their observations, a third of the galaxies are better fit as an obscured power law and another third are better fit as thermal emission. If these post-starburst galaxies, early in their transition, contain AGNs, then these are mostly confined to lower obscuration ( N H ≤ 10 23 cm −2 ) and lower luminosity ( L 2−10 keV ≤ 10 42 erg s −1 ). Two galaxies, however, are clearly best fit as significantly obscured AGNs. At least half of this sample shows evidence of at least low-luminosity AGN activity, though none could radiatively drive out the remaining molecular gas reservoirs. Therefore, these AGNs are more likely along for the ride, having been fed gas by the same processes driving the transition.