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  1. Halogens (F, Cl, Br, I) are primary components of volcanic gas emissions and play an essential role in continental arc magmatic environments due to their solubility in fluids that generate metallic ore deposits. Despite their ubiquity, the behavior and budget of halogens in continental arc environments are poorly constrained. We investigated the plutonic and volcanic halogen budgets in intermediate-to-felsic igneous rocks (56–77 wt% SiO2) from the Sierra Nevada (California) - a Mesozoic continental arc where plutonic and volcanic outcrops can be correlated via their geographic, compositional, and geochronologic framework. We measured the halogen concentrations of bulk rock powders and their leachates via ion chromatography (F, Cl) and ICP-MS (Br, I). Halogen concentrations in our rock powders range between 107–727 μg/g F, 13–316 μg/g Cl, 2–323 ng/g Br, and 1–69 ng/g I. In contrast, leachates yielded 3–4 orders of magnitude less Cl and F, one order of magnitude less I, and similar amounts of Br compared to their corresponding bulk rocks. Preliminary data show no significant differences between volcanic and plutonic samples, suggesting that halogen concentrations in these rocks are insensitive to shallow fractionation. Although F and I exhibit no correlation with major element compositions, Cl and Br display negative trends with increasing SiO2 and K2O, and positive trends with increasing Fe2O3T, MnO, MgO, CaO, and TiO2, suggesting mafic minerals as important hosts of structurally bound halogens. Overall, Sierran plutonic rocks display low halogen contents (max. F, Cl = 727, 315 μg/g), consistent with biotite- and apatite-bearing granitoids reported in [1]. This work suggests that halogens do not preferentially enrich in shallow plutonic or volcanic portions of a continental arc system and that mafic mineral phases likely serve as primary reservoirs of these elements in intermediate-to-felsic igneous rocks. These hypotheses will be further investigated in future work through in-situ analysis of halogen concentrations in crystals. [1] Teiber, Marks, Wenzel, Siebel, Altherr & Markl (2014), Chemical Geology, vol. 374–375, pp. 92–109, doi: 10.1016/j.chemgeo.2014.03.006 
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    Free, publicly-accessible full text available June 30, 2025
  2. Abstract

    The chemical and isotopic characteristics of a solidified pluton represent the integration of magmatic and sub-solidus processes operating across a range of spatial and temporal scales during pluton construction, crystallization, and cooling. Disentangling these processes and understanding where chemical and isotopic signatures were acquired requires the combination of multiple tools tracing processes at different time and length scales. We combine whole-rock oxygen and Sr-Nd isotopes, zircon oxygen isotopes and trace elements, and mineral compositions with published high-precision U-Pb zircon geochronology to evaluate differentiation within the bimodal Guadalupe Igneous Complex, Sierra Nevada, California (USA). The complex was constructed in ~300 k.y. between 149 and 150 Ma. Felsic magmas crystallized as centimeter- to meter-sized segregations in gabbros in the lower part of the complex and as granites and granophyres structurally above the gabbros. A central mingling zone separates the mafic and felsic units. Pluton-wide δ18O(whole-rock), δ18O(zircon), and Sr-Nd isotopic ranges are too large to be explained by in situ, closed-system differentiation, instead requiring open-system behavior at all scales. Low δ18O(whole-rock) and δ18O(zircon) values indicate assimilation of hydrothermally altered marine host rocks during ascent and/or emplacement. In situ differentiation processes operated on a smaller scale (meters to tens of meters) for at least ~200 k.y. via (1) percolation and segregation of chemically and isotopically diverse silicic interstitial melt from a heterogeneous gabbro mush; (2) crystal accumulation; and (3) sub-solidus, high-temperature, hydrothermal alteration at the shallow roof of the complex to modify the chemical and isotopic characteristics. Whole-rock and mineral chemistry in combination with geochronology allows deciphering open-system differentiation processes at the outcrop to pluton scale from magmatic to sub-solidus temperatures over time scales of hundreds of thousands to millions of years.

     
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    Free, publicly-accessible full text available May 17, 2025
  3. Abstract

    In ancient or partially eroded arc sections, a protracted history of tectonism and deformation makes interpretation of local volcanic-plutonic relationships challenging. The fragmentary preservation of volcanic rocks relative to the extensive plutonic record in upper-crustal arc sections also suggests that a broader-scale approach that includes volcanic-hypabyssal-plutonic “fields” is useful. In this context, studies of hypabyssal intrusions emplaced at the intersection of volcanic and plutonic fields provide additional physical and chemical constraints on shallow-level magmatic processes. New mapping, U-Pb zircon geochronology, and geochemistry at Tioga Pass, in the central Sierra Nevada arc section, document the physical and chemical evolution of the Tioga Pass hypabyssal complex, a ca. 100 Ma system that includes an intrusive dacite-rhyolite porphyry unit and comagmatic Tioga Lake quartz monzodiorite. We interpret these units as a Cretaceous subvolcanic magma feeder system intruding a package of tectonically displaced Triassic and Jurassic volcanic and sedimentary rocks, rather than the previous interpretation of a Triassic caldera. The Tioga Pass magmatic system is a well-exposed example of a hypabyssal complex with meso- to micro-scale structures that are consistent with rapid cooling and emplacement between 0–6 km depth and compositions suggestive of extensive fractionation of largely mantle-derived magma. The Tioga Pass porphyry unit is one of many hypabyssal intrusions scattered along a ~50-kilometer-wide belt of the east-central Sierra Nevada that are spatially associated with coeval volcanic and plutonic rocks due to tectonic downward transfer of arc crust. They provide a valuable perspective of shallow magmatic processes that may be used to test upper-crustal plutonic-volcanic links in tectonically reorganized arc sections.

     
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