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Abstract We have observed electron impact fluorescence from CO₂to excite the Cameron bands (CBs), CO (a³Π →X¹Σ⁺; 180–280 nm), the first-negative group (1NG) bands, CO⁺(B²Σ⁺→X²Σ⁺; 180–320 nm), the fourth-positive group (4PG) bands, CO (A¹Π →X¹Σ⁺; 111–280 nm), and the UV doublet, CO₂⁺( $\tilde{B}{}^2{\mathrm{\Sigma }}_u^{+}\to \tilde{X}{}^2{\mathrm{\Pi }}_g;$288.3 and 289.6 nm) in the ultraviolet (UV). This wavelength range matches the spectral region of past and present spacecraft equipped to observe UV dayglow and aurora emissions from the thermospheres (100–300 km) of Mars and Venus. Our large vacuum system apparatus is able to measure the emission cross sections of the strongest optically forbidden UV transitions found in planetary spectra. Based on our cross-sectional measurements, previous CB emission cross-sectional errors exceed a factor of 3. The UV doublet lifetime is perturbed through $\tilde{B}{}^2{\mathrm{\Sigma }}_u^{+}-\tilde{A}{}^2{\mathrm{\Pi }}_u$spin–orbit coupling. Forward modeling codes of the Mars dayglow have not been accurate in the mid-UV due to systematic errors in these two emission cross sections. We furnish absolute emission cross sections for several band systems over electron energies 20–100 eV for CO₂. We present a CB lifetime, which together with emission cross sections, furnish a set of fundamental physical constants for electron transport codes such as AURIC (Atmospheric Ultraviolet Radiance Integrated Code). AURIC and Trans-Mars are used in the analysis of UV spectra from the Martian dayglow and aurora. 

Abstract Current and previous thermospheric remote sensing missions use N₂Lyman‐Birge‐Hopfield (LBH) band dayglow emission measurements to retrieve line‐of‐sight thermospheric composition and temperature. The precision of thermospheric composition and temperature retrieved from observations depends on the uncertainty in the relative LBH vibrational populations. In the laboratory, electron impact induced LBH emission measurements have shown that the relative vibrational populations change with gas pressure. However, it is not fully understood how these populations change for dayglow observations where the emissions that contribute to the observations vary with solar illumination and line‐of‐sight geometry. We quantify the relative vibrational populations as a function of solar zenith angle (SZA) and tangent altitude using Global‐scale Observations of Limb and Disk mission's LBH dayglow observations. We find that, while some lower vibrational levels show potential enhancement with increasing pressure (decreasing altitude), in general, they do not change significantly with SZA or tangent altitude for dayglow observations. The vibrational populations can thus be assumed as fixed parameters when retrieving neutral disk temperatures from remotely sensed LBH dayglow observations. 

Abstract The geomagnetic storm on February 3, 2022 caused the loss of 38 Starlink satellites of Space‐X. The Global‐scale Observations of the Limb and Disk (GOLD) observations and Multi‐Scale Atmosphere Geospace Environment (MAGE) model simulations are utilized to investigate the thermospheric composition responses to the Space‐X storm. The percentage difference of the GOLD observed thermospheric O and N₂column density ratio (∑O/N₂) between the storm time (February 3, Day‐of‐Year [DOY] 34) and quiet time (DOY 32) shows a depletion region in the local noon sector mid‐high latitudes in the southern hemisphere, which corresponds to the east side of GOLD field‐of‐view (FOV). This is different from the classic theory of thermospheric composition disturbance during geomagnetic storms, under which the ∑O/N₂depletion is usually generated at local midnight and high latitudes, and thus, appear on the west side of GOLD FOV. MAGE simulations reproduce the observations qualitatively and indicate that the ∑O/N₂depletion is formed due to strong upwelling in the local morning caused by strong Joule heating. Interestingly, enhanced equatorward winds appear near local midnight, but also in the local morning sector, which transports ∑O/N₂depletion equatorward. The depletion corotates toward the local afternoon and is observed in the GOLD FOV. The equatorward winds in the local morning are due to the ion‐neutral coupling under the conditions of a dominant positive interplanetary magnetic field east‐west component (B_y) during the storm.