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ABSTRACT Formamide is a potentially important molecule in the context of pre-biotic chemistry, since reactions involving it can lead to precursors of genetic and metabolic molecules. Being abundant in cometary material and in star-forming regions, the formation and destruction routes of interstellar formamide have been the focus of several studies. In this work, we focus on the electron recombination of protonated formamide, an important step of its destruction routes, by performing rigorous ab initio calculations of this process. We found that our values are in good agreement with previous qualitative estimates of the global rate coefficients. On the contrary, we propose a substantial revision of the products and branching ratios. Finally, we justify and emphasize the importance of carrying out similar theoretical calculations on the largest possible number of complex species of astrochemical interest. 

Context. Protostellar jets are an important agent of star formation feedback, tightly connected with the mass-accretion process. The history of jet formation and mass ejection provides constraints on the mass accretion history and on the nature of the driving source. Aims. We characterize the time-variability of the mass-ejection phenomena at work in the class 0 protostellar phase in order to better understand the dynamics of the outflowing gas and bring more constraints on the origin of the jet chemical composition and the mass-accretion history. Methods. Using the NOrthern Extended Millimeter Array (NOEMA) interferometer, we have observed the emission of the CO 2–1 and SO N J = 5 4 –4 3 rotational transitions at an angular resolution of 1.0″ (820 au) and 0.4″ (330 au), respectively, toward the intermediate-mass class 0 protostellar system Cep E. Results. The CO high-velocity jet emission reveals a central component of ≤400 au diameter associated with high-velocity molecular knots that is also detected in SO, surrounded by a collimated layer of entrained gas. The gas layer appears to be accelerated along the main axis over a length scale δ 0 ~ 700 au, while its diameter gradually increases up to several 1000 au at 2000 au from the protostar. The jet is fragmented into 18 knots of mass ~10 −3 M ⊙ , unevenly distributed between the northern and southern lobes, with velocity variations up to 15 km s −1 close to the protostar. This is well below the jet terminal velocities in the northern (+ 65 km s −1 ) and southern (−125 km s −1 ) lobes. The knot interval distribution is approximately bimodal on a timescale of ~50–80 yr, which is close to the jet-driving protostar Cep E-A and ~150–20 yr at larger distances >12″. The mass-loss rates derived from knot masses are steady overall, with values of 2.7 × 10 −5 M ⊙ yr −1 and 8.9 × 10 −6 M ⊙ yr −1 in the northern and southern lobe, respectively. Conclusions. The interaction of the ambient protostellar material with high-velocity knots drives the formation of a molecular layer around the jet. This accounts for the higher mass-loss rate in the northern lobe. The jet dynamics are well accounted for by a simple precession model with a period of 2000 yr and a mass-ejection period of 55 yr.