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Abstract We combine multiple campaigns of K2 photometry with precision radial velocity measurements from Keck-HIRES to measure the masses of three sub-Neptune-sized planets. We confirm the planetary nature of the massive sub-Neptune K2-182 b ( P b = 4.7 days, R b = 2.69 R ⊕ ) and derive refined parameters for K2-199 b and c ( P b = 3.2 days, R b = 1.73 R ⊕ and P c = 7.4 days, R c = 2.85 R ⊕ ). These planets provide valuable data points in the mass–radius plane, especially as TESS continues to reveal an increasingly diverse sample of sub-Neptunes. The moderately bright ( V = 12.0 mag) early K dwarf K2-182 (EPIC 211359660) was observed during K2 campaigns 5 and 18. We find that K2-182 b is potentially one of the densest sub-Neptunes known to date (20 ± 5 M ⊕ and 5.6 ± 1.4 g cm −3 ). The K5V dwarf K2-199 (EPIC 212779596; V = 12.3 mag), observed in K2 campaigns 6 and 17, hosts two recently confirmed planets. We refine the orbital and planetary parameters for K2-199 b and c by modeling both campaigns of K2 photometry and adding 12 Keck-HIRES measurements to the existing radial velocity data set ( N = 33). We find that K2-199 b is likely rocky, at 6.9 ± 1.8 M ⊕ and 7.2 − 2.0 + 2.1 g cm −3 , and that K2-199 c has an intermediate density at 12.4 ± 2.3 M ⊕ and 2.9 − 0.6 + 0.7 g cm −3 . We contextualize these planets on the mass–radius plane, discuss a small but intriguing population of “superdense” sub-Neptunes ( R p < 3 R ⊕ , M p >20 M ⊕ ), and consider our prospects for the planets’ atmospheric characterization. 

Abstract The recent inference of sulfur dioxide (SO₂) in the atmosphere of the hot (approximately 1,100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations^1–3suggests that photochemistry is a key process in high-temperature exoplanet atmospheres⁴. This is because of the low (<1 ppb) abundance of SO₂under thermochemical equilibrium compared with that produced from the photochemistry of H₂O and H₂S (1–10 ppm)^4–9. However, the SO₂inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 μm and, therefore, the detection of other SO₂absorption bands at different wavelengths is needed to better constrain the SO₂abundance. Here we report the detection of SO₂spectral features at 7.7 and 8.5 μm in the 5–12-μm transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS)¹⁰. Our observations suggest an abundance of SO₂of 0.5–25 ppm (1σrange), consistent with previous findings⁴. As well as SO₂, we find broad water-vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 μm. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy-element content (metallicity) for WASP-39b of approximately 7.1–8.0 times solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range. 

Abstract Close-in giant exoplanets with temperatures greater than 2,000 K (‘ultra-hot Jupiters’) have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble Space Telescope (HST) and Spitzer Space Telescope^1–3. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis^3–12. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS¹³instrument on the JWST. The data span 0.85 to 2.85 μm in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at >6σconfidence) and evidence for optical opacity, possibly attributable to H⁻, TiO and VO (combined significance of 3.8σ). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy-element abundance (‘metallicity’,$${\rm{M/H}}=1.0{3}_{-0.51}^{+1.11}$$ $\mathrm{M/H}=1.03_{-0.51}^{+1.11}$times solar) and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the substellar point that decreases steeply and symmetrically with longitude towards the terminators. 

Abstract JWST has ushered in an era of unprecedented ability to characterize exoplanetary atmospheres. While there are over 5000 confirmed planets, more than 4000 Transiting Exoplanet Survey Satellite (TESS) planet candidates are still unconfirmed and many of the best planets for atmospheric characterization may remain to be identified. We present a sample of TESS planets and planet candidates that we identify as “best-in-class” for transmission and emission spectroscopy with JWST. These targets are sorted into bins across equilibrium temperatureT_eqand planetary radiusR_pand are ranked by a transmission and an emission spectroscopy metric (TSM and ESM, respectively) within each bin. We perform cuts for expected signal size and stellar brightness to remove suboptimal targets for JWST. Of the 194 targets in the resulting sample, 103 are unconfirmed TESS planet candidates, also known as TESS Objects of Interest (TOIs). We perform vetting and statistical validation analyses on these 103 targets to determine which are likely planets and which are likely false positives, incorporating ground-based follow-up from the TESS Follow-up Observation Program to aid the vetting and validation process. We statistically validate 18 TOIs, marginally validate 31 TOIs to varying levels of confidence, deem 29 TOIs likely false positives, and leave the dispositions for four TOIs as inconclusive. Twenty-one of the 103 TOIs were confirmed independently over the course of our analysis. We intend for this work to serve as a community resource and motivate formal confirmation and mass measurements of each validated planet. We encourage more detailed analysis of individual targets by the community. 

Abstract Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability¹. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program^2,3found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO₂) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M_J) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. ⁴). The most plausible way of generating SO₂in such an atmosphere is through photochemical processes^5,6. Here we show that the SO₂distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations⁷with NIRSpec PRISM (2.7σ)⁸and G395H (4.5σ)⁹. SO₂is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H₂S) is destroyed. The sensitivity of the SO₂feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO₂also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations. 

Abstract We report the discovery of HIP-97166b (TOI-1255b), a transiting sub-Neptune on a 10.3 day orbit around a K0 dwarf 68 pc from Earth. This planet was identified in a systematic search of TESS Objects of Interest for planets with eccentric orbits, based on a mismatch between the observed transit duration and the expected duration for a circular orbit. We confirmed the planetary nature of HIP-97166b with ground-based radial-velocity measurements and measured a mass of M b = 20 ± 2 M ⊕ along with a radius of R b = 2.7 ± 0.1 R ⊕ from photometry. We detected an additional nontransiting planetary companion with M c sin i = 10 ± 2 M ⊕ on a 16.8 day orbit. While the short transit duration of the inner planet initially suggested a high eccentricity, a joint RV-photometry analysis revealed a high impact parameter b = 0.84 ± 0.03 and a moderate eccentricity. Modeling the dynamics with the condition that the system remain stable over >10 5 orbits yielded eccentricity constraints e b = 0.16 ± 0.03 and e c < 0.25. The eccentricity we find for planet b is above average for the small population of sub-Neptunes with well-measured eccentricities. We explored the plausible formation pathways of this system, proposing an early instability and merger event to explain the high density of the inner planet at 5.3 ± 0.9 g cc −1 as well as its moderate eccentricity and proximity to a 5:3 mean-motion resonance. 

Abstract The Kepler and TESS missions have demonstrated that planets are ubiquitous. However, the success of these missions heavily depends on ground-based radial velocity (RV) surveys, which combined with transit photometry can yield bulk densities and orbital properties. While most Kepler host stars are too faint for detailed follow-up observations, TESS is detecting planets orbiting nearby bright stars that are more amenable to RV characterization. Here, we introduce the TESS-Keck Survey (TKS), an RV program using ∼100 nights on Keck/HIRES to study exoplanets identified by TESS. The primary survey aims are investigating the link between stellar properties and the compositions of small planets; studying how the diversity of system architectures depends on dynamical configurations or planet multiplicity; identifying prime candidates for atmospheric studies with JWST; and understanding the role of stellar evolution in shaping planetary systems. We present a fully automated target selection algorithm, which yielded 103 planets in 86 systems for the final TKS sample. Most TKS hosts are inactive, solar-like, main-sequence stars (4500 K ≤ T eff <6000 K) at a wide range of metallicities. The selected TKS sample contains 71 small planets ( R p ≤ 4 R ⊕ ), 11 systems with multiple transiting candidates, six sub-day-period planets and three planets that are in or near the habitable zone ( S inc ≤ 10 S ⊕ ) of their host star. The target selection described here will facilitate the comparison of measured planet masses, densities, and eccentricities to predictions from planet population models. Our target selection software is publicly available and can be adapted for any survey that requires a balance of multiple science interests within a given telescope allocation. 

Abstract The Saturn-mass exoplanet WASP-39b has been the subject of extensive efforts to determine its atmospheric properties using transmission spectroscopy^1–4. However, these efforts have been hampered by modelling degeneracies between composition and cloud properties that are caused by limited data quality^5–9. Here we present the transmission spectrum of WASP-39b obtained using the Single-Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument on the JWST. This spectrum spans 0.6–2.8 μm in wavelength and shows several water-absorption bands, the potassium resonance doublet and signatures of clouds. The precision and broad wavelength coverage of NIRISS/SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favouring a heavy-element enhancement (‘metallicity’) of about 10–30 times the solar value, a sub-solar carbon-to-oxygen (C/O) ratio and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are also best explained by wavelength-dependent, non-grey clouds with inhomogeneous coverageof the planet’s terminator.