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The radial transport, or drift, of dust has taken a critical role in giant planet formation theory. However, it has been challenging to identify dust drift pileups in the hard-to-observe inner disk. We find that the IM Lup disk shows evidence that it has been shaped by an episode of dust drift. Using radiative transfer and dust dynamical modeling we study the radial and vertical dust distribution. We find that high dust drift rates exceeding 110M_⊕Myr⁻¹are necessary to explain both the dust and CO observations. Furthermore, the bulk of the large dust present in the inner 20 au needs to be vertically extended, implying high turbulence (α_z≳ 10⁻³) and small grains (0.2–1 mm). We suggest that this increased level of particle stirring is consistent with the inner dust-rich disk undergoing turbulence triggered by the vertical shear instability. The conditions in the IM Lup disk imply that giant planet formation through pebble accretion is only effective outside of 20 au. If such an early, high-turbulence inner region is a natural consequence of high dust drift rates, then this has major implications for understanding the formation regions of giant planets including Jupiter and Saturn.

Abstract The chemical composition of the inner region of protoplanetary disks can trace the composition of planetary-building material. The exact elemental composition of the inner disk has not yet been measured and tensions between models and observations still exist. Recent advancements have shown UV shielding to be able to increase the emission of organics. Here, we expand on these models and investigate how UV shielding may impact chemical composition in the inner 5 au. In this work, we use the model from Bosman et al. and expand it with a larger chemical network. We focus on the chemical abundances in the upper disk atmosphere where the effects of water UV shielding are most prominent and molecular lines originate. We find rich carbon and nitrogen chemistry with enhanced abundances of C 2 H 2 , CH 4 , HCN, CH 3 CN, and NH 3 by >3 orders of magnitude. This is caused by the self-shielding of H 2 O, which locks oxygen in water. This subsequently results in a suppression of oxygen-containing species like CO and CO 2 . The increase in C 2 H 2 seen in the model with the inclusion of water UV shielding allows us tomore »explain the observed C 2 H 2 abundance without resorting to elevated C/O ratios as water UV shielding induced an effectively oxygen-poor environment in oxygen-rich gas. Thus, water UV shielding is important for reproducing the observed abundances of hydrocarbons and nitriles. From our model result, species like CH 4 , NH 3 , and NO are expected to be observable with the James Webb Space Telescope (JWST).« less

Abstract An understanding of abundance and distribution of water vapor in the innermost region of protoplanetary disks is key to understanding the origin of habitable worlds and planetary systems. Past observations have shown H 2 O to be abundant and a major carrier of elemental oxygen in disk surface layers that lie within the inner few astronomical units of the disk. The combination of high abundance and strong radiative transitions leads to emission lines that are optically thick across the infrared spectral range. Its rarer isotopologue H 2 18 O traces deeper into this layer and will trace the full content of the planet-forming zone. In this work, we explore the relative distribution of H 2 16 O and H 2 18 O within a model that includes water self-shielding from the destructive effects of ultraviolet radiation. In this Letter we show that there is an enhancement in the relative H 2 18 O abundance high up in the warm molecular layer within 0.1–10 au due to self-shielding of CO, C 18 O, and H 2 O. Most transitions of H 2 18 O that can be observed with JWST will partially emit from this layer, making it essential tomore »take into account how H 2 O self-shielding may effect the H 2 O to H 2 18 O ratio. Additionally, this reservoir of H 2 18 O -enriched gas in combination with the vertical “cold finger” effect might provide a natural mechanism to account for oxygen isotopic anomalies found in meteoritic material in the solar system.« less

Carbon dioxide is an important tracer of the chemistry and physics in the terrestrial planet-forming zone. Using a thermochemical model that has been tested against the mid-infrared water emission, we reinterpret the CO₂emission as observed with Spitzer. We find that both water UV-shielding and extra chemical heating significantly reduce the total CO₂column in the emitting layer. Water UV-shielding is the more efficient effect, reducing the CO₂column by ∼2 orders of magnitude. These lower CO₂abundances lead to CO₂-to-H₂O flux ratios that are closer to the observed values, but CO₂emission is still too bright, especially in relative terms. Invoking the depletion of elemental oxygen outside of the water midplane ice line more strongly impacts the CO₂emission than it does the H₂O emission, bringing the CO₂-to-H₂O emission in line with the observed values. We conclude that the CO₂emission observed with Spitzer-IRS is coming from a thin layer in the photosphere of the disk, similar to the strong water lines. Below this layer, we expect CO₂not to be present except when replenished by a physical process. This would be visible in the¹³CO₂spectrum as well as certain¹²CO₂features that can be observed by JWST-MIRI.

Abstract The water snowline in circumstellar disks is a crucial component in planet formation, but direct observational constraints on its location remain sparse owing to the difficulty of observing water in both young embedded and mature protoplanetary disks. Chemical imaging provides an alternative route to locate the snowline, and HCO + isotopologues have been shown to be good tracers in protostellar envelopes and Herbig disks. Here we present ∼0.″5 resolution (∼35 au radius) Atacama Large Millimeter/submillimeter Array (ALMA) observations of HCO + J = 4 − 3 and H 13 CO + J = 3 − 2 toward the young (Class 0/I) disk L1527 IRS. Using a source-specific physical model with the midplane snowline at 3.4 au and a small chemical network, we are able to reproduce the HCO + and H 13 CO + emission, but for HCO + only when the cosmic-ray ionization rate is lowered to 10 −18 s −1 . Even though the observations are not sensitive to the expected HCO + abundance drop across the snowline, the reduction in HCO + above the snow surface and the global temperature structure allow us to constrain a snowline location between 1.8 and 4.1 au. Deep observations aremore »required to eliminate the envelope contribution to the emission and to derive more stringent constraints on the snowline location. Locating the snowline in young disks directly with observations of H 2 O isotopologues may therefore still be an alternative option. With a direct snowline measurement, HCO + will be able to provide constraints on the ionization rate.« less

Mid-infrared spectroscopy is one of the few ways to observe the composition of the terrestrial planet-forming zone, the inner few astronomical units, of protoplanetary disks. The species currently detected in the disk atmosphere, for example, CO, CO₂, H₂O, and C₂H₂, are theoretically enough to constrain the C/O ratio on the disk surface. However, thermochemical models have difficulties in reproducing the full array of detected species in the mid-infrared simultaneously. In an effort to get closer to the observed spectra, we have included water UV-shielding as well as more efficient chemical heating into the thermochemical code Dust and Lines. We find that both are required to match the observed emission spectrum. Efficient chemical heating, in addition to traditional heating from UV photons, is necessary to elevate the temperature of the water-emitting layer to match the observed excitation temperature of water. We find that water UV-shielding stops UV photons from reaching deep into the disk, cooling down the lower layers with a higher column. These two effects create a hot emitting layer of water with a column of 1–10 × 10¹⁸cm⁻². This is only 1%–10% of the water column above the dustτ= 1 surface at mid-infrared wavelengths in the models andmore »represents <1% of the total water column.

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Gas mass is a fundamental quantity of protoplanetary disks that directly relates to their ability to form planets. Because we are unable to observe the bulk H₂content of disks directly, we rely on indirect tracers to provide quantitative mass estimates. Current estimates for the gas masses of the observed disk population in the Lupus star-forming region are based on measurements of isotopologues of CO. However, without additional constraints, the degeneracy between H₂mass and the elemental composition of the gas leads to large uncertainties in such estimates. Here, we explore the gas compositions of seven disks from the Lupus sample representing a range of CO-to-dust ratios. With Band 6 and 7 ALMA observations, we measure line emission for HCO⁺, HCN, and N₂H⁺. We find a tentative correlation among the line fluxes for these three molecular species across the sample, but no correlation with¹³CO or submillimeter continuum fluxes. For the three disks where N₂H⁺is detected, we find that a combination of high disk gas masses and subinterstellar C/H and O/H are needed to reproduce the observed values. We find increases of ∼10–100× previous mass estimates are required to match the observed line fluxes. This work highlights how multimolecular studies are essentialmore »for constraining the physical and chemical properties of the gas in populations of protoplanetary disks, and that CO isotopologues alone are not sufficient for determining the mass of many observed disks.

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Abstract The water snowline location in protostellar envelopes provides crucial information about the thermal structure and the mass accretion process as it can inform about the occurrence of recent (≲1000 yr) accretion bursts. In addition, the ability to image water emission makes these sources excellent laboratories to test indirect snowline tracers such as H 13 CO + . We study the water snowline in five protostellar envelopes in Perseus using a suite of molecular-line observations taken with the Atacama Large Millimeter/submillimeter Array (ALMA) at ∼0.″2−0.″7 (60–210 au) resolution. B1-c provides a textbook example of compact H 2 18 O (3 1,3 −2 2,0 ) and HDO (3 1,2 −2 2,1 ) emission surrounded by a ring of H 13 CO + ( J = 2−1) and HC 18 O + ( J = 3−2). Compact HDO surrounded by H 13 CO + is also detected toward B1-bS. The optically thick main isotopologue HCO + is not suited to trace the snowline, and HC 18 O + is a better tracer than H 13 CO + due to a lower contribution from the outer envelope. However, because a detailed analysis is needed to derive a snowline location from H 13 COmore »+ or HC 18 O + emission, their true value as a snowline tracer will lie in the application in sources where water cannot be readily detected. For protostellar envelopes, the most straightforward way to locate the water snowline is through observations of H 2 18 O or HDO. Including all subarcsecond-resolution water observations from the literature, we derive an average burst interval of ∼10,000 yr, but high-resolution water observations of a larger number of protostars are required to better constrain the burst frequency.« less