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Creators/Authors contains: "Bertrand, Guy"

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  1. Free, publicly-accessible full text available April 30, 2026
  2. Free, publicly-accessible full text available May 7, 2026
  3. The bis-monosubstituted aminocarbene-P2adduct is a generator of P2, under the classical triple-bonded form (PP), but it also acts as a bis(phosphinidene) (P–P) synthetic equivalent. 
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    Free, publicly-accessible full text available October 2, 2025
  4. Chiral NHCs have found numerous applications as ligands for transition metals and in their own right for asymmetric catalysis. We report a synthetic route froml-malic acid to enantiopure 1,2,3-triazoliums with the chiral center in a fused ring. 
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  5. A novel family of cyclic (alkyl)(amino)carbenes, which we name cyclic (amino)(barrelene)carbenes (CABCs) is reported. The key synthetic step involves an intramolecular [4+2] cyclization of an anthracene derivative with an alkyne. This synthetic approach allows for the attachment of both aryl and alkyl groups on the nitrogen atom. When used as ligand, two of the barrelene hydrogens are in close contact with the metal, which could stabilize low valent catalytic intermediates. 
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