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Abstract. Measurements of multiple cosmogenic nuclides in a single sample are valuable for various applications of cosmogenic nuclide exposure dating and allow for correcting exposure ages for surface weathering and erosion and establishing exposure–burial history. Here we provide advances in the measurement of cosmogenic 10Be in pyroxene and constraints on the production rate that provide new opportunities for measurements of multi-nuclide systems, such as 10Be/3He, in pyroxene-bearing samples. We extracted and measured cosmogenic 10Be in pyroxene from two sets of Ferrar Dolerite samples collected from the Transantarctic Mountains in Antarctica. One set of samples has 10Be concentrations close to saturation, which allows for the production rate calibration of 10Be in pyroxene by assuming production–decay equilibrium. The other set of samples, which has a more recent exposure history, is used to determine if a rapid fusion method can be successfully applied to samples with Holocene to Last Glacial Maximum exposure ages. From measured 10Be concentrations in the near-saturation sample set we find the production rate of 10Be in pyroxene to be 3.74 ± 0.10 atoms g−1 yr−1, which is consistent with 10Be/3He paired nuclide ratios from samples assumed to have simple exposure. Given the high 10Be concentration measured in this sample set, a sample mass of ∼ 0.5 g of pyroxene is sufficient for the extraction of cosmogenic 10Be from pyroxene using a rapid fusion method. However, for the set of samples that have low 10Be concentrations, measured concentrations were higher than expected. We attribute spuriously high 10Be concentrations to failure in removing all meteoric 10Be and/or a highly variable and poorly quantified procedural blank background correction. 

Rapid sediment accumulation rates (SAR) in a fan delta situated on the rapidly uplifting footwall of the Taormina normal fault in NE Sicily preserves a rare record of earthquakes and base level change for a tightly coupled source to sink system. We use this sedimentary archive to reconstruct the kinematics and slip history of the fault and further an understanding of how tectonic forcing across various scales are encoded in stratigraphy. A revised luminescence-based age model indicates that ~82 m of the Pagliara fan-delta foreset facies was deposited in ~11 ka at a mean SAR of ~0.74 cm/yr during MIS 7. Syn-depositional terrestrial cosmogenic nuclide (TCN) determined paleoerosion rates of 0.91±0.12 mm/yr and 1.31 ±0.61 mm/yr are similar to published modern erosion rates for the Pagliara basin of 0.97 ±0.11 mm/yr. At the stratigraphic scale, a time series of magnetic susceptibility (c) sampled at 1 m intervals in the foresets displays four ~2,800 yr / 20 m-thick cycles of growing c, bounded by sharp decreases that do not coincide with changes in sediment texture. The c of the low-grade metamorphic bedrock in the source is 20-100 times weaker than the c of rubified soils mantling the hillslopes, which is comparable to the c of the delta sediments. We propose that large, bedrock-cored landslides quasi-periodically deliver weak c sediment to the delta that dilutes a c signal otherwise dominated by the stripping of soil-mantled hillslopes. We propose that centennial-scale recurrence interval earthquakes are most capable at triggering a basin-scale landslide only after channel incision has increased relief of hillslopes to the threshold condition, which requires millennia to achieve. At the landscape scale of delta geometry and location, the Pagliara delta accumulated in a hanging wall basin that has since been inverted. We reconstruct the history of base level fall for the delta from an inversion of fluvial topography and apportion that record to its rock uplift, delta deposition, and eustatic components. We show that footwall uplift has been unsteady over the past 600 ka ranging from -1 to 3 mm/yr. The integration of our stratigraphic- and landscape scale observations furthers our understanding of the natural hazards related to normal fault earthquakes and their impact on sediment dynamics in this steep, active tectonic setting. 

Abstract. To understand the erosivity of the eastern portion of the Laurentide Ice Sheet and the isotopic characteristics of the sediment it transported, we sampled buried sand from deglacial features (eskers and deltas) across eastern Canada (n = 10), a landscape repeatedly covered by the Quebec-Labrador Ice Dome. We measured concentrations of 10Be and 26Al in quartz isolated from the sediment and, after correcting for sub-surface cosmic-ray exposure after Holocene deglaciation, used these results to determine nuclide concentrations at the time the ice sheet deposited the sediment. To determine what percentage of sediment moving through streams and rivers currently draining the field area was derived from incision of thick glacial deposits as opposed to surface erosion, we used 10Be and 26Al as tracers by collecting and analyzing modern river sand sourced from Holocene-exposed landscapes (n = 11). We find that all ten deglacial sediment samples contain measurable concentrations of 10Be and 26Al equivalent on average to several thousand years of surface exposure – after correction, based on sampling depth, for Holocene nuclide production after deposition. Error-weighted averages (1 standard deviation errors) of measured 26Al/10Be ratios for both corrected deglacial (6.1 ± 1.2) and modern sediment samples (6.6 ± 0.5) are slightly lower than the production ratio at high latitudes (7.3 ± 0.3) implying burial and preferential decay of 26Al, the shorter-lived nuclide. However, five deglacial samples collected closer to the center of the former Quebec-Labrador Ice Dome have much lower corrected 26Al/10Be ratios (5.2 ± 0.8) than five samples collected closer to the former ice margins (7.0 ± 0.7). Modern river sand contains on average about 1.75 times the concentration of both nuclides compared to deglacial sediment corrected for Holocene exposure. The ubiquitous presence of 10Be and 26Al in eastern Quebec deglacial sediment is consistent with many older-than-expected exposure ages, reported here and by others, for bedrock outcrops and boulders once covered by the Quebec-Labrador Ice Dome. Together, these data suggest that glacial erosion and sediment transport in eastern Canada were insufficient to remove material containing cosmogenic nuclides produced during prior interglacial periods both from at least some bedrock outcrops and from all glacially transported sediment we sampled. Near the center of the Quebec-Labrador Ice Dome, ratios of 26Al/10Be are below those characteristic of surface production at high latitude. This suggests burial of the glacially transported sediment for at least many hundreds of thousands of years and the possibility that ice at the center of the Quebec-Labrador Ice Dome survived many interglacials when more distal ice melted away. 

The persistence and size of the Greenland Ice Sheet (GrIS) through the Pleistocene is uncertain. This is important because reconstructing changes in the GrIS determines its contribution to sea level rise during prior warm climate periods and informs future projections. To understand better the history of Greenland’s ice, we analyzed glacial till collected in 1993 from below 3 km of ice at Summit, Greenland. The till contains plant fragments, wood, insect parts, fungi, and cosmogenic nuclides showing that the bed of the GrIS at Summit is a long-lived, stable land surface preserving a record of deposition, exposure, and interglacial ecosystems. Knowing that central Greenland was tundra-covered during the Pleistocene informs the understanding of Arctic biosphere response to deglaciation. 

Abstract. In 1966, drilling at Camp Century, Greenland, recovered 3.44 meters of sub-glacial material from beneath 1350 meters of ice. Although prior analysis of this material showed that the core includes glacial sediment, ice, and sediment deposited during an interglacial, the sub-glacial material had never been thoroughly studied. To better characterize this material, we analyzed 26 of the 30 core samples remaining in the archive. We performed a multi-scale analysis including X-ray diffraction, micro-computed tomography, and scanning electron microscopy to delineate stratigraphic units and assign facies based on inferred depositional processes. At the macro-scale, quantitative X-ray diffraction revealed that quartz and feldspar dominated the sediment and that there was insignificant variation in relative mineral abundance between samples. Meso-scale evaluation of the frozen material using micro-computed tomography scans showed clear variations in the stratigraphy of the core characterized by the presence of bedding, grading, and sorting. Micro-scale grain size and shape analysis, conducted using scanning electron microscopy, showed an abundance of fine-grained materials in the lower part of the core and no correspondence between grain shape parameters and sedimentary structures. These multiscale data define 5 distinct stratigraphic units within the core based on sedimentary process; K-means clustering analysis supports this proposed unit delineation. Our observations suggest that ice retreat uncovered the Camp Century region exposing basal till, covered with a remnant of basal ice or firn (Units 1 and 2). Continued ice-free conditions led to till disruption by liquid water causing a slump deposit (Unit 3) and the development of a small fluvial system of increasing energy up core (Units 4–5). Analysis of the Camp Century sub-glacial material indicates a diverse stratigraphy preserved below the ice that recorded episodes of glaciated and deglaciated conditions in northwestern Greenland. Our physical, geochemical, and mineralogic analyses reveal a history of deposition, weathering, and sediment transport preserved under the ice and show the promise of sub-glacial materials to increase our knowledge of past ice sheet behavior over time. 

We test the hypothesis that glacier systems, located in continental regions proximal to the Laurentide Ice Sheet (LIS), had local ice maxima considerably earlier than the LIS maximum and thus before the insolation minima at ~21 ka. Ranges located in the northwest US exhibit earlier deglaciation timing between ~23 and 22 ka, except for the Yellowstone region where younger time-transgressive ages complicate regional interpretations and the northern Montana ice cap where late glacial ages have recently been produced. Constraining the glacial history of more ice sheet-proximal alpine glaciers provides insight into whether the contrasting maximum-ice times in the northern Rocky Mountains were caused by regional climatic differences, such as anticyclonic wind patterns driven by the presence of the LIS. In the Pioneer Mountains of Montana, we measured in situ cosmogenic 10Be in 35 boulders on moraines marking the maximum Late Pleistocene positions of alpine glaciers from three valleys. The 10Be samples produced a range of ages, spanning pre Bull Lake to the last glaciation (i.e., Pinedale/Marine Isotope Stage (MIS) 2). We find an average exposure age for initial deglaciation of 18.2 ±0.9 during the local Last Glacial Maximum, indicative of synchronous retreat in the Pioneer Mountains. The similarity of initial deglaciation timing of the Pioneer Mountain glaciers with the northwestern Yellowstone glacial system and northern MT ice cap suggests that topography more proximal to the LIS margin maintained full ice extent longer. Our findings, in context of previous work, suggest that in the case of the Pioneer Mountains their more proximal location to the ice margin may have delayed onset of deglaciation by greater exposure to local cooling from katabatic winds and/or additional moisture sourced from large ice-marginal glacial lakes, hence the lack of earlier deglacial ages like those found further to the west and east of the northern Rocky Mountain cordillera. 

Constraining the timing and rate of Laurentide Ice Sheet (LIS) retreat through the northeastern United States is important for understanding the co-evolution of complex climatic and glaciologic events that characterized the end of the Pleistocene epoch. However, no in situ cosmogenic 10Be exposure age estimates for LIS retreat exist through large parts of Connecticut or Massachusetts. Due to the large disagreement between radiocarbon and 10Be ages constraining LIS retreat at the maximum southern margin and the paucity of data in central New England, the timing of LIS retreat through this region is uncertain. Here, we date LIS retreat through south-central New England using 14 new in situ cosmogenic 10Be exposure ages measured in samples collected from bedrock and boulders. Our results suggest ice retreated entirely from Connecticut by 18.3 ± 0.3 ka (n = 3). In Massachusetts, exposure ages from similar latitudes suggest ice may have occupied the Hudson River Valley up to 2 kyr longer (15.2 ± 0.3 ka, average, n = 2) than the Connecticut River Valley (17.4 ± 1.0 ka, average, n = 5). We use these new ages to provide insight about LIS retreat timing during the early deglacial period and to explore the mismatch between radiocarbon and cosmogenic deglacial age chronologies in this region. 

Temporal and spatial variations of tectonic rock uplift are generally thought to be the main controls on long-term erosion rates in various landscapes. However, rivers continuously lengthen and capture drainages in strike-slip fault systems due to ongoing motion across the fault, which can induce changes in landscape forms, drainage networks, and local erosion rates. Located along the restraining bend of the San Andreas Fault, the San Bernardino Mountains provide a suitable location for assessing the influence of topographic disequilibrium from perturbations by tectonic forcing and channel reorganization on measured erosion rates. In this study, we measured 17 new basin-averaged erosion rates using cosmogenic 10Be in river sands (hereafter, 10Be-derived erosion rates) and compiled 31 10Be-derived erosion rates from previous work. We quantify the degree of topographic disequilibrium using topographic analysis by examining hillslope and channel decoupling, the areal extent of pre-uplift surface, and drainage divide asymmetry across various landscapes. Similar to previous work, we find that erosion rates generally increase from north to south across the San Bernardino Mountains, reflecting a southward increase in tectonic activity. However, a comparison between 10Be-derived erosion rates and various topographic metrics in the southern San Bernardino Mountains suggests that the presence of transient landscape features such as relict topography and drainage-divide migration may explain local variations in 10Be-derived erosion rates. Our work shows that coupled analysis of erosion rates and topographic metrics provides tools for assessing the influence of tectonic uplift and channel reorganization on landscape evolution and 10Be-derived erosion rates in an evolving strike-slip restraining bend. 

Abstract. Basal materials in ice cores hold information about paleoclimate conditions, glacial processes, and the timing of past ice-free intervals, all of which aid understanding of ice sheet stability and its contribution to sea level rise in a warming climate. Only a few cores have been drilled through ice sheets into the underlying sediment and bedrock, producing limited material for analysis. The last of three Camp Century ice cores, which the U.S. Army collected in northwestern Greenland from 1963–1966 CE, recovered about 3.5 m of subglacial material, including ice and sediment. Here, we document the scientific history of the Camp Century subglacial material. We present our recent core-cutting, sub-sampling, and processing methodology and results for this unique archive. In 1972 CE, curators at the Buffalo, New York, Ice Core Laboratory cut the original core sections into 32 segments that were each about 10 cm long. Since then, two segments were lost and are unaccounted for, two were thawed, and two were cut as pilot samples in 2019 CE. Except for the two thawed segments, the rest of the extant core has remained frozen since collection. In 2021 CE, we documented, described, and then cut each of the remaining frozen archived segments (n=26). We saved an archival half and cut the working half into eight oriented sub-samples under controlled temperature and light conditions for physical, geochemical, isotopic, sedimentological, magnetic, and biological analyses. Our approach was designed to maximize sample usage for multiproxy analysis, minimize contamination, and preserve archive material for future analyses of this legacy subglacial material. Grain size, bulk density, sedimentary features, magnetic susceptibility, and ice content, as well as pore ice pH and conductivity, suggest that the basal sediment contains five stratigraphic units. We interpret these stratigraphic units as representing different depositional environments in subglacial or ice-free conditions: from bottom to top, a diamicton with subhorizontal ice lenses (Unit 1), vertically fractured ice with dispersed fine-grained sediments (<20 % in mass) (Unit 2), a normally graded bed of pebbles to very fine sand in an icy matrix (Unit 3), bedded very fine to fine sand (Unit 4), and stratified medium to coarse sand (Unit 5). Plant macrofossils are present in all samples and are most abundant in Units 3 and 4; insect remains are present in some samples (Units 1, 3, and 5). Our approach provides a working template for future studies of ice core basal materials because it includes intentional planning of core sub-sampling, processing methodologies, and archiving strategies to optimize the collection of paleoclimate, glacial process, geochemical, geochronological, and sediment properties from archives of limited size. Our work benefited from a carefully curated and preserved archive, allowing the application of analytical techniques not available in 1966 CE. Preserving uncontaminated core material for future analyses that use currently unavailable tools and techniques is an important consideration for rare archive materials such as these from Camp Century.