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Abstract Young, self-luminous super-Jovian companions discovered by direct imaging provide a challenging test for planet formation and evolution theories. By spectroscopically characterizing the atmospheric compositions of these super-Jupiters, we can constrain their formation histories. Here we present studies of the recently discovered HIP 99770 b, a 16M_Juphigh-contrast companion on a 17 au orbit, using the fiber-fed high-resolution spectrograph KPIC ( $\mathcal{R}$∼ 35,000) on the Keck II telescope. OurK-band observations led to detections of H₂O and CO in the atmosphere of HIP 99770 b. We carried out free retrieval analyses usingpetitRADTRANSto measure its chemical abundances, including the metallicity and C/O ratio, projected rotation velocity ( $v\sin i$), and radial velocity (RV). We found that the companion’s atmosphere has C/O $={0.55}_{-0.04}^{+0.06}$and [M/H] $={0.26}_{-0.23}^{+0.24}$(1σconfidence intervals), values consistent with those of the Sun and with a companion formation via gravitational instability or core accretion. The projected rotation velocity $v\sin \left(i\right)<7.8$km s⁻¹is small relative to other directly imaged companions with similar masses and ages. This may imply a nearly pole-on orientation or effective magnetic braking by a circumplanetary disk. In addition, we added the companion-to-primary relative RV measurement to the orbital fitting and obtained updated constraints on orbital parameters. Detailed characterization of super-Jovian companions within 20 au like HIP 99770 b is critical for understanding the formation histories of this population. 

Abstract We explore terrestrial planet formation with a focus on the supply of solid-state organics as the main source of volatile carbon. For the water-poor Earth, the water ice line, or ice sublimation front, within the planet-forming disk has long been a key focal point. We posit that the soot line, the location where solid-state organics are irreversibly destroyed, is also a key location within the disk. The soot line is closer to the host star than the water snow line and overlaps with the location of the majority of detected exoplanets. In this work, we explore the ultimate atmospheric composition of a body that receives a major portion of its materials from the zone between the soot line and water ice line. We model a silicate-rich world with 0.1% and 1% carbon by mass with variable water content. We show that as a result of geochemical equilibrium, the mantle of these planets would be rich in reduced carbon but have relatively low water (hydrogen) content. Outgassing would naturally yield the ingredients for haze production when exposed to stellar UV photons in the upper atmosphere. Obscuring atmospheric hazes appear common in the exoplanetary inventory based on the presence of often featureless transmission spectra. Such hazes may be powered by the high volatile content of the underlying silicate-dominated mantle. Although this type of planet has no solar system counterpart, it should be common in the galaxy with potential impact on habitability. 

Abstract The JWST Disk Infrared Spectral Chemistry Survey (JDISCS) aims to understand the evolution of the chemistry of inner protoplanetary disks using the Mid-InfraRed Instrument (MIRI) on the James Webb Space Telescope (JWST). With a growing sample of >30 disks, the survey implements a custom method to calibrate the MIRI Medium Resolution Spectrometer (MRS) to contrasts of better than 1:300 across its 4.9–28μm spectral range. This is achieved using observations of Themis family asteroids as precise empirical reference sources. The high spectral contrast enables precise retrievals of physical parameters, searches for rare molecular species and isotopologues, and constraints on the inventories of carbon- and nitrogen-bearing species. JDISCS also offers significant improvements to the MRS wavelength and resolving power calibration. We describe the JDISCS calibrated data and demonstrate their quality using observations of the disk around the solar-mass young star FZ Tau. The FZ Tau MIRI spectrum is dominated by strong emission from warm water vapor. We show that the water and CO line emission originates from the disk surface and traces a range of gas temperatures of ∼500–1500 K. We retrieve parameters for the observed CO and H₂O lines and show that they are consistent with a radial distribution represented by two temperature components. A high water abundance ofn(H₂O) ∼ 10⁻⁴fills the disk surface at least out to the 350 K isotherm at 1.5 au. We search the FZ Tau environs for extended emission, detecting a large (radius of ∼300 au) ring of emission from H₂gas surrounding FZ Tau, and discuss its origin. 

Abstract We present high-resolutionK-band emission spectra of the quintessential hot Jupiter HD 189733 b from the Keck Planet Imager and Characterizer. Using a Bayesian retrieval framework, we fit the dayside pressure–temperature profile, orbital kinematics, mass-mixing ratios of H₂O, CO, CH₄, NH₃, HCN, and H₂S, and the¹³CO/¹²CO ratio. We measure mass fractions of ${\mathrm{logH}}_2\mathrm{O}=-{2.0}_{-0.4}^{+0.4}$and $\mathrm{logCO}=-{2.2}_{-0.5}^{+0.5}$, and place upper limits on the remaining species. Notably, we find logCH₄< −4.5 at 99% confidence, despite its anticipated presence at the equilibrium temperature of HD 189733 b assuming local thermal equilibrium. We make a tentative (∼3σ) detection of¹³CO, and the retrieved posteriors suggest a¹²C/¹³C ratio similar to or substantially less than the local interstellar value. The possible¹³C enrichment would be consistent with accretion of fractionated material in ices or in the protoplanetary disk midplane. The retrieved abundances correspond to a substantially substellar atmospheric C/O = 0.3 ± 0.1, while the carbon and oxygen abundances are stellar to slightly superstellar, consistent with core-accretion models which predict an inverse correlation between C/O and metallicity. The specific combination of low C/O and high metallicity suggests significant accretion of solid material may have occurred late in the formation process of HD 189733 b. 

Abstract We present Keck Planet Imager and Characterizer (KPIC) high-resolution (R∼35,000)K-band thermal emission spectroscopy of the ultrahot Jupiter WASP-33b. The use of KPIC’s single-mode fibers greatly improves both blaze and line-spread stabilities relative to slit spectrographs, enhancing the cross-correlation detection strength. We retrieve the dayside emission spectrum with a nested-sampling pipeline, which fits for orbital parameters, the atmospheric pressure–temperature profile, and the molecular abundances. We strongly detect the thermally inverted dayside and measure mass-mixing ratios for CO ( ${\mathrm{logCO}}_{\mathrm{MMR}}=-{1.1}_{-0.6}^{+0.4}$), H₂O ( ${\mathrm{logH}}_2{\mathrm{O}}_{\mathrm{MMR}}=-{4.1}_{-0.9}^{+0.7}$), and OH ( ${\mathrm{logOH}}_{\mathrm{MMR}}=-{2.1}_{-1.1}^{+0.5}$), suggesting near-complete dayside photodissociation of H₂O. The retrieved abundances suggest a carbon- and possibly metal-enriched atmosphere, with a gas-phase C/O ratio of ${0.8}_{-0.2}^{+0.1}$, consistent with the accretion of high-metallicity gas near the CO₂snow line and post-disk migration or with accretion between the soot and H₂O snow lines. We also find tentative evidence for¹²CO/¹³CO ∼ 50, consistent with values expected in protoplanetary disks, as well as tentative evidence for a metal-enriched atmosphere (2–15 × solar). These observations demonstrate KPIC’s ability to characterize close-in planets and the utility of KPIC’s improved instrumental stability for cross-correlation techniques. 

Abstract Gas mass is a fundamental quantity of protoplanetary disks that directly relates to their ability to form planets. Because we are unable to observe the bulk H₂content of disks directly, we rely on indirect tracers to provide quantitative mass estimates. Current estimates for the gas masses of the observed disk population in the Lupus star-forming region are based on measurements of isotopologues of CO. However, without additional constraints, the degeneracy between H₂mass and the elemental composition of the gas leads to large uncertainties in such estimates. Here, we explore the gas compositions of seven disks from the Lupus sample representing a range of CO-to-dust ratios. With Band 6 and 7 ALMA observations, we measure line emission for HCO⁺, HCN, and N₂H⁺. We find a tentative correlation among the line fluxes for these three molecular species across the sample, but no correlation with¹³CO or submillimeter continuum fluxes. For the three disks where N₂H⁺is detected, we find that a combination of high disk gas masses and subinterstellar C/H and O/H are needed to reproduce the observed values. We find increases of ∼10–100× previous mass estimates are required to match the observed line fluxes. This work highlights how multimolecular studies are essential for constraining the physical and chemical properties of the gas in populations of protoplanetary disks, and that CO isotopologues alone are not sufficient for determining the mass of many observed disks.