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Abstract The formation and evolution pathway for the directly imaged multiplanetary system HR 8799 remains mysterious. Accurate constraints on the chemical composition of the planetary atmosphere(s) are key to solving the mystery. We perform a detailed atmospheric retrieval on HR 8799 c to infer the chemical abundances and abundance ratios using a combination of photometric data along with low- and high-resolution spectroscopic data ( R ∼ 20–35,000). We specifically retrieve [C/H], [O/H], and C/O and find them to be 0.55 − 0.39 + 0.36 , 0.47 − 0.32 + 0.31 , and 0.67 − 0.15 + 0.12 at 68% confidence. The superstellar C and O abundances, yet a stellar C/O ratio, reveal a potential formation pathway for HR 8799 c. Planet c, and likely the other gas giant planets in the system, formed early on (likely within ∼1 Myr), followed by further atmospheric enrichment in C and O through the accretion of solids beyond the CO ice line. The enrichment either preceded or took place during the early phase of the inward migration to the current planet locations.

The Orion Kleinmann-Low nebula (Orion KL) is notoriously complex and exhibits a range of physical and chemical components. We conducted high-angular-resolution (subarcsecond) observations of¹³CH₃OHν= 0 (∼0.″3 and ∼0.″7) and CH₃CNν₈= 1 (∼0.″2 and ∼0.″9) line emission with the Atacama Large Millimeter/submillimeter Array (ALMA) to investigate Orion KL’s structure on small spatial scales (≤350 au). Gas kinematics, excitation temperatures, and column densities were derived from the molecular emission via a pixel-by-pixel spectral line fitting of the image cubes, enabling us to examine the small-scale variation of these parameters. Subregions of the Hot Core have a higher excitation temperature in a 0.″2 beam than in a 0.″9 beam, indicative of possible internal sources of heating. Furthermore, the velocity field includes a bipolar ∼7–8 km s⁻¹feature with a southeast–northwest orientation against the surrounding ∼4–5 km s⁻¹velocity field, which may be due to an outflow. We also find evidence of a possible source of internal heating toward the Northwest Clump, since the excitation temperature there is higher in a smaller beam versus a larger beam. Finally, the region southwest of the Hot Core (Hot Core-SW) presents itself as a particularly heterogeneous region bridging the Hot Core and Compact Ridge. Additional studies to identifymore »the (hidden) sources of luminosity and heating within Orion KL are necessary to better understand the nebula and its chemistry.

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Gas mass is a fundamental quantity of protoplanetary disks that directly relates to their ability to form planets. Because we are unable to observe the bulk H₂content of disks directly, we rely on indirect tracers to provide quantitative mass estimates. Current estimates for the gas masses of the observed disk population in the Lupus star-forming region are based on measurements of isotopologues of CO. However, without additional constraints, the degeneracy between H₂mass and the elemental composition of the gas leads to large uncertainties in such estimates. Here, we explore the gas compositions of seven disks from the Lupus sample representing a range of CO-to-dust ratios. With Band 6 and 7 ALMA observations, we measure line emission for HCO⁺, HCN, and N₂H⁺. We find a tentative correlation among the line fluxes for these three molecular species across the sample, but no correlation with¹³CO or submillimeter continuum fluxes. For the three disks where N₂H⁺is detected, we find that a combination of high disk gas masses and subinterstellar C/H and O/H are needed to reproduce the observed values. We find increases of ∼10–100× previous mass estimates are required to match the observed line fluxes. This work highlights how multimolecular studies are essentialmore »for constraining the physical and chemical properties of the gas in populations of protoplanetary disks, and that CO isotopologues alone are not sufficient for determining the mass of many observed disks.

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Abstract Direct imaging studies have mainly used low-resolution spectroscopy ( R ∼ 20–100) to study the atmospheres of giant exoplanets and brown dwarf companions, but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances (e.g., carbon-to-oxygen ratio, metallicity). This precludes clear insights into the formation mechanisms of these companions. The Keck Planet Imager and Characterizer (KPIC) uses adaptive optics and single-mode fibers to transport light into NIRSPEC ( R ∼ 35,000 in the K band), and aims to address these challenges with high-resolution spectroscopy. Using an atmospheric retrieval framework based on petitRADTRANS , we analyze the KPIC high-resolution spectrum (2.29–2.49 μ m) and the archival low-resolution spectrum (1–2.2 μ m) of the benchmark brown dwarf HD 4747 B ( m = 67.2 ± 1.8 M Jup , a = 10.0 ± 0.2 au, T eff ≈ 1400 K). We find that our measured C/O and metallicity for the companion from the KPIC high-resolution spectrum agree with those of its host star within 1 σ –2 σ . The retrieved parameters from the K -band high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum aremore »highly sensitive to our chosen cloud model. Finally, we detect CO, H 2 O, and CH 4 (volume-mixing ratio of log(CH 4 ) = −4.82 ± 0.23) in this L/T transition companion with the KPIC data. The relative molecular abundances allow us to constrain the degree of chemical disequilibrium in the atmosphere of HD 4747 B, and infer a vertical diffusion coefficient that is at the upper limit predicted from mixing length theory.« less

Abstract A benchmark brown dwarf (BD) is a BD whose properties (e.g., mass and chemical composition) are precisely and independently measured. Benchmark BDs are valuable in testing theoretical evolutionary tracks, spectral synthesis, and atmospheric retrievals for substellar objects. Here, we report results of atmospheric retrieval on a synthetic spectrum and a benchmark BD, HR 7672 B, with petitRADTRANS . First, we test the retrieval framework on a synthetic PHOENIX BT-Settl spectrum with a solar composition. We show that the retrieved C and O abundances are consistent with solar values, but the retrieved C/O is overestimated by 0.13–0.18, which is about four times higher than the formal error bar. Second, we perform retrieval on HR 7672 B using high spectral-resolution data ( R = 35,000) from the Keck Planet Imager and Characterizer and near-infrared photometry. We retrieve [C/H], [O/H], and C/O to be −0.24 ± 0.05, −0.19 ± 0.04, and 0.52 ± 0.02. These values are consistent with those of HR 7672 A within 1.5 σ . As such, HR 7672 B is among only a few benchmark BDs (along with Gl 570 D and HD 3651 B) that have been demonstrated to have consistent elemental abundances with their primary stars.more »Our work provides a practical procedure of testing and performing atmospheric retrieval, and sheds light on potential systematics of future retrievals using high- and low-resolution data.« less

Two-dimensional Raman and hybrid terahertz-Raman spectroscopic techniques provide invaluable insight into molecular structures and dynamics of condensed-phase systems. However, corroborating experimental results with theory is difficult due to the high computational cost of incorporating quantum-mechanical effects in the simulations. Here, we present the equilibrium–nonequilibrium ring-polymer molecular dynamics (RPMD), a practical computational method that can account for nuclear quantum effects on the two-time response function of nonlinear optical spectroscopy. Unlike a recently developed approach based on the double Kubo transformed (DKT) correlation function, our method is exact in the classical limit, where it reduces to the established equilibrium-nonequilibrium classical molecular dynamics method. Using benchmark model calculations, we demonstrate the advantages of the equilibrium–nonequilibrium RPMD over classical and DKT-based approaches. Importantly, its derivation, which is based on the nonequilibrium RPMD, obviates the need for identifying an appropriate Kubo transformed correlation function and paves the way for applying real-time path-integral techniques to multidimensional spectroscopy.