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A thin liquid droplet spreads on a soft viscoelastic substrate with arbitrary rheology. Lubrication theory is applied to the governing field equations in the liquid and solid domains, which are coupled through the free boundary at the solid–liquid interface, to derive a set of reduced equations that describe the spreading dynamics. Fourier transform techniques and the finite difference method are used to construct a solution for the dynamic liquid–gas and solid–liquid interface shapes, as well as the macroscopic contact angle. Substrate properties affect the spreading dynamics through the contact angle and internal droplet flow fields, and these mechanisms are revealed. Increased substrate softness increases the spreading rate, whereas increased viscoelasticity decreases the spreading rate. For the case of a purely elastic substrate, the spreading power-law exponent recovers Tanner's law in the rigid limit and increases with substrate softness.more » « less
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Thin-film flow down a fibre exhibits rich dynamics and is relevant to applications such as desalination, fibre coating and fog harvesting. These flows are subject to instabilities that result in dynamic bead-on-fibre patterns. We perform an experimental study of shear-thinning flow down fibres using 20 different xanthan gum solutions as our working liquid. The bead-on-fibre morphology can be oriented either symmetrically or asymmetrically on the fibre, and this depends upon the surface tension, fibre diameter and liquid rheology, as defined by the Ostwald power-law index. For highly shear-thinning liquids, it is possible for the pattern to be complex and exhibit simultaneously both asymmetric large beads and symmetric small beads in the isolated and convective flow regimes. We quantify the transition between flow regimes and bead dynamics for the asymmetric morphology, and compare with Newtonian flow, as it depends upon the experimental parameters. Finally, the dimensionless bead frequency is shown to scale with the Bond number for all of our experimental data (symmetric and asymmetric).more » « less
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Abstract A soft viscoelastic drop has dynamics governed by the balance between surface tension, viscosity, and elasticity, with the material rheology often being frequency dependent, which are utilized in bioprinting technologies for tissue engineering and drop-deposition processes for splash suppression. We study the free and forced oscillations of a soft viscoelastic drop deriving (1) the dispersion relationship for free oscillations, and (2) the frequency response for forced oscillations, of a soft material with arbitrary rheology. We then restrict our analysis to the classical cases of a Kelvin–Voigt and Maxwell model, which are relevant to soft gels and polymer fluids, respectively. We compute the complex frequencies, which are characterized by an oscillation frequency and decay rate, as they depend upon the dimensionless elastocapillary and Deborah numbers and map the boundary between regions of underdamped and overdamped motions. We conclude by illustrating how our theoretical predictions for the frequency-response diagram could be used in conjunction with drop-oscillation experiments as a “drop vibration rheometer”, suggesting future experiments using either ultrasonic levitation or a microgravity environment.more » « less
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