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From Magnetic Chains to Sheets: The Impact of Hydrofluoric Acid Quantities in Mild Hydrothermal Synthesis on Mixed-Metal Fluoride Formation

https://doi.org/10.1021/acs.chemmater.4c03524

Keerthisinghe, Navindra; Morrison, Gregory; Breton, Logan S; Smith, Mark D; Zhang, Qiang; Kirkham, Melanie J; Klepov, Vladislav V; zur_Loye, Hans-Conrad (March 2025, Chemistry of Materials)

Free, publicly-accessible full text available March 11, 2026
Sensitivity of Mild Hydrothermal Synthesis to the Reaction Conditions: Targeting Mixed-Metal Hexagonal Tungsten Bronze Fluorides A _x M ²⁺ _x M ³⁺ _(1–x) F ₃ to Investigate Their Magnetic Behavior

https://doi.org/10.1021/acs.inorgchem.4c02307

Masachchi, Lakshani W; Keerthisinghe, Navindra; Berseneva, Anna A; Morrison, Gregory; Smith, Mark D; Breton, Logan S; Schorne-Pinto, Juliano; Aziziha, Mina; zur_Loye, Hans-Conrad (September 2024, Inorganic Chemistry)

Free, publicly-accessible full text available September 23, 2025
Polymorphism in A ₃ MF ₆ (A = Rb, Cs; M = Al, Ga) grown using mixed halide fluxes

https://doi.org/10.1039/D3DT00352C

Morrison, Gregory; Masachchi, Lakshani W.; Tisdale, Hunter B.; Chang, Tieyan; Jones, Virginia G.; Zamorano, K. Pilar; Breton, Logan S.; Smith, Mark D.; Chen, Yu-Sheng; zur Loye, Hans-Conrad (June 2023, Dalton Transactions)

Single crystals of A₃MF₆(A = Rb, Cs; M = Al, Ga) were grown from mixed alkali chloride/fluoride fluxes. The polymorphism of each compound was studiedviaTGA/DSC and high temperature X-ray diffraction.
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Synthesis, structure, and scintillation of Rb4Ta2Si8O23

https://doi.org/10.1016/j.solidstatesciences.2022.106861

Carone, Darren; Jacobsohn, Luiz G.; Breton, Logan S.; zur Loye, Hans-Conrad (May 2022, Solid State Sciences)

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Synthesis of Hydrated Ternary Lanthanide-Containing Chlorides Exhibiting X-ray Scintillation and Luminescence

https://doi.org/10.1021/acs.inorgchem.1c02004

Ayer, Gyanendra B.; Smith, Mark D.; Jacobsohn, Luiz G.; Morrison, Gregory; Tisdale, Hunter B.; Breton, Logan S.; Zhang, Weiguo; Halasyamani, P. Shiv; zur Loye, Hans-Conrad (October 2021, Inorganic Chemistry)

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