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  1. Free, publicly-accessible full text available May 23, 2023
  2. The molecular catalyst diacetyl-bis( N -4-methyl-3-thiosemi-carbazonato)nickel( ii ) (NiATSM) was integrated with Si for light-driven hydrogen evolution from water. Compared to an equivalent loading of Ni metal, the NiATSM/p-Si electrode performed better. Durability of the surface-bound catalyst under operation in acid was achieved without covalent attachment by using Nafion binding.