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Abstract Bio‐enabled and bio‐mimetic nanomaterials represent functional materials, which use bio‐derived materials and synthetic components to bring the better of two, natural and synthetic, worlds. Prospective broad applications are flexibility and mechanical strength of lightweight structures, adaptive photonic functions and chiroptical activity, ambient processing and sustainability, and potential scalability along with broad sensing/communication abilities. Here, we summarize recent results on relevant functional photonic materials with responsive behavior under mechanical stresses, magnetic field, and changing chemical environment. We focus on recent achievements and trends in tuning optical materials' properties such as light scattering, absorption and reflection, light emission, structural colors, optical birefringence, linear and circular polarization for prospective applications in biosensing, optical communication, optical encoding, fast actuation, biomedical fields, and tunable optical appearance. 

Here, we present a novel approach to address this issue by combining MXene (Ti3C2Tx) nanosheets with branched ionic nanoparticles from polyhedral oligomeric silsesquioxanes (POSS) using an amphiphilicity driven assembly for the formation of composite monolayers of nanoparticle-decorated MXene nanosheets at the air-water interface. The amphiphilic hybrid MXene/POSS monolayers allow for the fabrication of organized multilayered films with ionic nanoparticles supporting nanoscale gap between MXene nanosheets. For these composite multilayers we observed a 400% enhancement in specific capacitance compared to pure drop-cast MXene films. Furthermore, dramatically enhanced electrochemical cycling stability for ultrathin film electrodes (< 400 nm in thickness) with a 91% capacitance retention over 10,000 cycles has been achieved. Our results suggest that this insertion of 0D ionic nanoparticles with complementary interactions in-between 2D MXene nanosheets could be extended to other hybrid 0D-2D nanomaterials, providing a promising pathway for the development of hybrid electrode architectures with enhanced ionic transport for long term energy cycling and storage, capacitive deionization, and ionic filtration. 

Abstract Natural polymers, particularly plant‐derived nanocelluloses, self‐organize into hierarchical structures, enabling mechanical robustness, bright iridescence, emission, and polarized light reflection. These biophotonic properties are facilitated by the assembly of individual components during evaporation, such as cellulose nanocrystals (CNCs), which exhibit a left‐handed helical pitch in a chiral nematic state. This work demonstrates how optically active films with pre‐programmed opposite handedness (left or right) can be constructed via shear‐induced twisted printing with clockwise and counter‐clockwise shearing vectors. The resulting large‐area thin films are transparent yet exhibit pre‐determined mirror‐symmetrical optical activity, enabling the distinction of absorbed and emitted circularly polarized light. This processing method allows for sequential printing of thin and ultrathin films with twisted layered organization and on‐demand helicity. The complex light polarization behavior is due to step‐like changes in linear birefringence within each deposited layer and circular birefringence, different from that of conventional CNC films as revealed with Muller matrix analysis. Furthermore, intercalating an achiral organic dye into printed structures induces circularly polarized luminescence while preserving high transmittance and controlled handedness. These results suggest that twisted sequential printing can facilitate the construction of chiroptical metamaterials with tunable circular polarization, absorption, and emission for optical filters, encryption, photonic coatings, and chiral sensors.