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Abstract This study presents an experimental investigation to examine the mixed‐mode fracture behavior of fused filament fabrication printed acrylonitrile butadiene styrene (ABS). The single‐edge notch bending specimen configuration is employed to perform mixed‐mode fracture experiments. Four distinct printing orientations—90°, 0°, 45°/−45°, and 90°—are investigated. For each orientation, fracture studies are conducted under pure mode‐I loading (symmetric three‐point bending), mixed‐mode I/II, and pure mode‐II loading (asymmetric three‐point bending) to establish a mixed‐mode fracture criterion. The study evaluates the influence of printing orientation on fracture toughness, crack propagation behavior, and the mixed‐mode fracture criterion. Scanning electron microscopy (SEM) is utilized to analyze the fracture surfaces and correlate the observed fracture mechanisms with the measured fracture toughness values. The findings reveal that printing orientation significantly affects both the fracture toughness and the mixed‐mode fracture criterion. Among the orientations studied, the 90° specimens exhibit the highest fracture toughness and superior performance under all mixed‐mode conditions. SEM images of the fracture surfaces across different printing orientations show the formation of smooth shear zones of varying sizes near the crack tip under mixed‐mode and pure mode‐II conditions. These zones suggest an enhanced resistance to crack propagation, with the degree of improvement differing among the orientations. HighlightsMixed‐mode fracture behavior of 3D‐printed acrylonitrile butadiene styrene.Printing orientations have a major influence on mixed‐mode fracture criterion.90° printing orientation has the highest fracture toughness for mode‐mixities.0° printing orientation has the lowest fracture toughness for mode‐mixities.Fracture surface has dominant shear zone for all mode‐mixities except mode‐I.