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Claude, Guilhem; Salsi, Federico; Hagenbach, Adelheid; Gembicky, Milan; Neville, Michael; Chan, Chinglin; Figueroa, Joshua S.; Abram, Ulrich (, Organometallics)
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Salsi, Federico; Neville, Michael; Drance, Myles; Hagenbach, Adelheid; Chan, Chinglin; Figueroa, Joshua S.; Abram, Ulrich (, Chemical Communications)The mixed isocyanide/carbonyl complexes cis - and trans -[Re(CO) 3 Br(CNAr Dipp2 ) 2 ] (Ar Dipp2 = 2,6-(2,6-(i-Pr) 2 C 6 H 3 ) 2 C 6 H 3 ) can be synthesized from reactions of [Re(CO) 5 Br] and CNAr Dipp2 depending on the conditions applied. Reduction of the neutral Re( i ) species gives the monoanionic complex [Re(CO) 3 (CNAr Dipp2 ) 2 ] − or the neutral [Re(CO) 3 (CNAr Dipp2 ) 2 ], which contain rhenium in the formal oxidation states “−1” and “0”, respectively.more » « less
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Mokhtarzadeh, Charles C.; Chan, Chinglin; Moore, Curtis E.; Rheingold, Arnold L.; Figueroa, Joshua S. (, Journal of the American Chemical Society)