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Creators/Authors contains: "Chandrashekar, Hediyala B."

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  1. ; ; ; ; ; ; ; ( , Angewandte Chemie)
    Abstract

    Directed C−H functionalization has been realized as a complimentary technique to achieve borylation at a distal position of aliphatic amines. Here, we demonstrated the oxidative borylation at the distal δ‐position of aliphatic amines using various borylating agents, a palladium catalyst, and a rightly tuned ligand in the presence of a cheap oxidant. Moreover, an organopalladium δ‐C(sp3)‐H‐activated intermediate has been isolated and crystallographically characterized to get mechanistic insight.

     
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  2. ; ; ; ; ; ; ; ( , Angewandte Chemie International Edition)
    Abstract

    Directed C−H functionalization has been realized as a complimentary technique to achieve borylation at a distal position of aliphatic amines. Here, we demonstrated the oxidative borylation at the distal δ‐position of aliphatic amines using various borylating agents, a palladium catalyst, and a rightly tuned ligand in the presence of a cheap oxidant. Moreover, an organopalladium δ‐C(sp3)‐H‐activated intermediate has been isolated and crystallographically characterized to get mechanistic insight.

     
    more » « less