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Element isotopes are characterized by distinct atomic masses and nuclear spins, which can significantly influence material properties. Notably, however, isotopes in natural materials are homogenously distributed in space. Here, we propose a method to configure material properties by repositioning isotopes in engineered van der Waals (vdW) isotopic heterostructures. We showcase the properties of hexagonal boron nitride (hBN) isotopic heterostructures in engineering confined photon-lattice waves—hyperbolic phonon polaritons. By varying the composition, stacking order, and thicknesses of h¹⁰BN and h¹¹BN building blocks, hyperbolic phonon polaritons can be engineered into a variety of energy-momentum dispersions. These confined and tailored polaritons are promising for various nanophotonic and thermal functionalities. Due to the universality and importance of isotopes, our vdW isotope heterostructuring method can be applied to engineer the properties of a broad range of materials.

 

Recent technology development of logic devices based on 2-D semiconductors such as MoS2, WS2, and WSe2 has triggered great excitement, paving the way to practical applications. Making low-resistance p-type contacts to 2-D semiconductors remains a critical challenge. The key to addressing this challenge is to find high-work function metallic materials which also introduce minimal metal-induced gap states (MIGSs) at the metal/semiconductor interface. In this work, we perform a systematic computational screening of novel metallic materials and their heterojunctions with monolayer WSe2 based on ab initio density functional theory and quantum device simulations. Two contact strategies, van der Waals (vdW) metallic contact and bulk semimetallic contact, are identified as promising solutions to achieving Schottky-barrier-free and low-contact-resistance p-type contacts for WSe2 p-type field-effect transistor (pFETs). Good candidates of p-type contact materials are found based on our screening criteria, including 1H-NbS2, 1H-TaS2, and 1T-TiS2 in the vdW metal category, as well as Co3Sn2S2 and TaP in the bulk semimetal category. Simulations of these new p-type contact materials suggest reduced MIGS, less Fermi-level pinning effect, negligible Schottky barrier height and small contact resistance (down to 20 Ωμm ) 

Use of structured roles to facilitate cooperative learning is an evidence-based practice that has been shown to improve student performance, attitude, and persistence. The combination of structured roles and activities also helps build students’ process skills including communication and metacognition. While these benefits have been shown in a variety of disciplines, most prior work has focused on in-person, synchronous settings, and few studies have looked at online, synchronous settings. With the ongoing COVID-19 pandemic, we need a better understanding of how cooperative learning takes place online and what differences may exist between online and in-person modalities. This work-in-progress serves to document our development of an observation protocol to help us answer research questions such as the following: Do group members participate equally? Do group members’ contributions match their role? How do groups connect and bond with each other? How do groups seek help? 

Black hat hackers use malicious exploits to circumvent security controls and take advantage of system vulnerabilities worldwide, costing the global economy over $450 billion annually. While many organizations are increasingly turning to cyber threat intelligence (CTI) to help prioritize their vulnerabilities, extant CTI processes are often criticized as being reactive to known exploits. One promising data source that can help develop proactive CTI is the vast and ever-evolving Dark Web. In this study, we adopted the computational design science paradigm to design a novel deep learning (DL)-based exploit-vulnerability attention deep structured semantic model (EVA-DSSM) that includes bidirectional processing and attention mechanisms to automatically link exploits from the Dark Web to vulnerabilities. We also devised a novel device vulnerability severity metric (DVSM) that incorporates the exploit post date and vulnerability severity to help cybersecurity professionals with their device prioritization and risk management efforts. We rigorously evaluated the EVA-DSSM against state-of-the-art non-DL and DL-based methods for short text matching on 52,590 exploit-vulnerability linkages across four testbeds: web application, remote, local, and denial of service. Results of these evaluations indicate that the proposed EVA-DSSM achieves precision at 1 scores 20% - 41% higher than non-DL approaches and 4% - 10% higher than DL-based approaches. We demonstrated the EVA-DSSM’s and DVSM’s practical utility with two CTI case studies: openly accessible systems in the top eight U.S. hospitals and over 20,000 Supervisory Control and Data Acquisition (SCADA) systems worldwide. A complementary user evaluation of the case study results indicated that 45 cybersecurity professionals found the EVA-DSSM and DVSM results more useful for exploit-vulnerability linking and risk prioritization activities than those produced by prevailing approaches. Given the rising cost of cyberattacks, the EVA-DSSM and DVSM have important implications for analysts in security operations centers, incident response teams, and cybersecurity vendors. 

Black hat hackers use malicious exploits to circumvent security controls and take advantage of system vulnerabilities worldwide, costing the global economy over $450 billion annually. While many organizations are increasingly turning to cyber threat intelligence (CTI) to help prioritize their vulnerabilities, extant CTI processes are often criticized as being reactive to known exploits. One promising data source that can help develop proactive CTI is the vast and ever-evolving Dark Web. In this study, we adopted the computational design science paradigm to design a novel deep learning (DL)-based exploit-vulnerability attention deep structured semantic model (EVA-DSSM) that includes bidirectional processing and attention mechanisms to automatically link exploits from the Dark Web to vulnerabilities. We also devised a novel device vulnerability severity metric (DVSM) that incorporates the exploit post date and vulnerability severity to help cybersecurity professionals with their device prioritization and risk management efforts. We rigorously evaluated the EVA-DSSM against state-of-the-art non-DL and DL-based methods for short text matching on 52,590 exploit-vulnerability linkages across four testbeds: web application, remote, local, and denial of service. Results of these evaluations indicate that the proposed EVA-DSSM achieves precision at 1 scores 20%-41% higher than non-DL approaches and 4%-10% higher than DL-based approaches. We demonstrated the EVA-DSSM's and DVSM's practical utility with two CTI case studies: openly accessible systems in the top eight U.S. hospitals and over 20,000 Supervisory Control and Data Acquisition (SCADA) systems worldwide. A complementary user evaluation of the case study results indicated that 45 cybersecurity professionals found the EVA-DSSM and DVSM results more useful for exploit-vulnerability linking and risk prioritization activities than those produced by prevailing approaches. Given the rising cost of cyberattacks, the EVA-DSSM and DVSM have important implications for analysts in security operations centers, incident response teams, and cybersecurity vendors. 

International dark web platforms operating within multiple geopolitical regions and languages host a myriad of hacker assets such as malware, hacking tools, hacking tutorials, and malicious source code. Cybersecurity analytics organizations employ machine learning models trained on human-labeled data to automatically detect these assets and bolster their situational awareness. However, the lack of human-labeled training data is prohibitive when analyzing foreign-language dark web content. In this research note, we adopt the computational design science paradigm to develop a novel IT artifact for cross-lingual hacker asset detection(CLHAD). CLHAD automatically leverages the knowledge learned from English content to detect hacker assets in non-English dark web platforms. CLHAD encompasses a novel Adversarial deep representation learning (ADREL) method, which generates multilingual text representations using generative adversarial networks (GANs). Drawing upon the state of the art in cross-lingual knowledge transfer, ADREL is a novel approach to automatically extract transferable text representations and facilitate the analysis of multilingual content. We evaluate CLHAD on Russian, French, and Italian dark web platforms and demonstrate its practical utility in hacker asset profiling, and conduct a proof-of-concept case study. Our analysis suggests that cybersecurity managers may benefit more from focusing on Russian to identify sophisticated hacking assets. In contrast, financial hacker assets are scattered among several dominant dark web languages. Managerial insights for security managers are discussed at operational and strategic levels.