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Martin, Jovan San; Zeng, Xianghua; Chen, Xihan; Miller, Collin; Han, Chuang; Lin, Yixiong; Yamamoto, Nobuyuki; Wang, Xiaoming; Yazdi, Sadegh; Yan, Yanfa; et al (, Journal of the American Chemical Society)
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Ma, Xuejian; Zhang, Fei; Chu, Zhaodong; Hao, Ji; Chen, Xihan; Quan, Jiamin; Huang, Zhiyuan; Wang, Xiaoming; Li, Xiaoqin; Yan, Yanfa; et al (, Nature Communications)Abstract The outstanding performance of organic-inorganic metal trihalide solar cells benefits from the exceptional photo-physical properties of both electrons and holes in the material. Here, we directly probe the free-carrier dynamics in Cs-doped FAPbI3thin films by spatiotemporal photoconductivity imaging. Using charge transport layers to selectively quench one type of carriers, we show that the two relaxation times on the order of 1 μs and 10 μs correspond to the lifetimes of electrons and holes in FACsPbI3, respectively. Strikingly, the diffusion mapping indicates that the difference in electron/hole lifetimes is largely compensated by their disparate mobility. Consequently, the long diffusion lengths (3~5 μm) of both carriers are comparable to each other, a feature closely related to the unique charge trapping and de-trapping processes in hybrid trihalide perovskites. Our results unveil the origin of superior diffusion dynamics in this material, crucially important for solar-cell applications.more » « less
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Wang, Kang; Lu, Haipeng; Zhu, Xiaolin; Lin, Yixiong; Beard, Matthew C.; Yan, Yong; Chen, Xihan (, ACS Energy Letters)
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Lu, Haipeng; Zhu, Xiaolin; Miller, Collin; San Martin, Jovan; Chen, Xihan; Miller, Elisa M.; Yan, Yong; Beard, Matthew C. (, The Journal of Chemical Physics)
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