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Visualizing the alignment of lone pair electrons in La ₃ AsS ₅ Br ₂ and La ₅ As ₂ S ₉ Cl ₃ to form an acentric or centrosymmetric structure

https://doi.org/10.1039/D3CE00834G

Cicirello, Andrea; Swindle, Andrew; Wang, Jian (November 2023, CrystEngComm)

Heteroanionic chalcohalides La₃AsS₅Br₂and La₅As₂S₉Cl₃exhibit a good example of how alignment of lone pair electrons affects the formation of acentric crystal structure.
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