Ultrahigh‐pressure (UHP) rocks in North‐East Greenland lie within a larger region of high‐pressure Laurentian crust formed in the overthickened upper plate of the collision with Baltica. Coesite‐bearing zircon dates UHP metamorphism to 365–350 Ma, which formed at the end of the Caledonian collision as a result of intracontinental subduction facilitated by strike‐slip faults that broke the lithosphere. Rutile is the stable Ti‐bearing phase at UHP, while titanite forms on the retrograde path. Trace elements and U‐Pb in titanite were analyzed for six UHP gneisses. Zr‐in‐titanite temperatures range from 764 to 803°C and lie on the isobaric part of the pressure‐temperature path at 1.2 GPa, which fits Ti‐phase stability determined by thermodynamic modeling. Large (>600 μm), zoned titanite preserves three distinct trace element patterns that are due to metamorphism, melting and garnet breakdown. Weighted mean206Pb/238U ages range from 347 ± 5 Ma to 320 ± 11 Ma, but age variation as a function of trace element domain for individual samples is not resolvable within uncertainty. Titanite records a prolonged period of exhumation that is also seen in the zircon record, where phengite decompression melting started at ca. 347 Ma, leucosome emplacement accompanied retrograde metamorphism from 350 to 330 Ma; and titanite grew during isobaric cooling from 345 to 320 Ma when the UHP rocks stalled at lower crustal levels. The same transforms that originally break the lithosphere play a significant role in channeling the UHP rocks back to the lower crust via buoyancy driven exhumation, after which time titanite formed.
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Abstract Garnet–kyanite–staurolite assemblages with large, late porphyroblasts of amphibole form garbenschists in Ordovician volcaniclastic rocks lying immediately south of the Pearya terrane on northernmost Ellesmere Island, Canada. The schist, which together with carbonate olistoliths makes up the Petersen Bay Assemblage (PBA), displays a series of parallel isograds that mark an increase in metamorphic grade over a distance of 10 km towards the contact with Pearya; however, a steep, brittle Cenozoic strike-slip fault with an unknown amount displacement disturbs the earlier accretionary relationship. The late amphibole growth, probably due to fluid ingress, is clear evidence of disequilibrium conditions in the garbenschist. In order to recover the P–T history of the schists, we construct isochemical phase equilibrium models for a nearby garnet–mica schist that escaped the fluid event and compare the results to quartz inclusion in garnet (QuiG) barometry for a garbenschist and the metapelitic garnet schist. Quartz inclusions are confined to garnet cores and the QuiG results, combined with Ti-in-biotite and garnet–biotite thermometry, delineate a prograde path from 480 to 600°C and 0.7 to 0.9 GPa. This path agrees with growth zoning in garnet deduced from X-ray maps of the spessartine component in garnet. The peak conditions obtained from pseudosection modelling using effective bulk composition and the intersection of garnet rim with matrix biotite and white mica isopleths in the metapelite are 665°C at ≤0.85 GPa. Three generations of monazite (I, II and III) were identified by textural characterization, geochemical composition (REE and Y concentrations) and U–Pb ages measured by ion microprobe. Monazite I occurs in the matrix and as inclusions in garnet rims and grew at peak P–T conditions at 397 ± 2 Ma (2σ) from the breakdown of allanite. Monazite II forms overgrowths on matrix Monazite I grains that are oriented parallel to the main schistosity and yield ages of 385 ± 2 Ma. Monazite III, found only in the garbenschist, is 374 ± 6 Ma, which is interpreted as the time of amphibole growth during fluid infiltration at lower temperature and pressure on a clockwise P–T path that remained in the kyanite stability field. These results point to a relatively short (≈12 Myr) Barrovian metamorphic event that affected the schists of the PBA. An obvious heat source is lacking in the adjacent Pearya terrane, but we speculate it was large Devonian plutons—similar to the 390 ± 10 Ma Cape Woods granite located 40 km across strike from the fault—that have been excised by strike-slip. Arc fragments that are correlative to the PBA are low grade; they never saw the heat and were not directly involved in Pearya accretion.more » « less
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Abstract Iceland's oldest silicic rocks provide unique insight into the island's early crustal evolution. We present new zircon U‐Pb ages bolstered with zircon trace element and isotopic compositions, and whole rock Nd, Hf, and Pb isotope compositions, from three silicic magmatic centers—Hrafnsfjörður, Árnes, and Kaldalón—to understand the petrogenesis of large silicic volcanic centers in the northern Westfjords, Iceland. Our data confirm Hrafnsfjörður as the oldest known central volcano in Iceland (∼14 Ma) and establish an older age for Árnes (∼13 Ma) than previously estimated. We also report the first U‐Pb zircon dates from Kaldalón (∼13.5 Ma). Zircon oxygen isotope compositions range from δ18O∼+2 to +4‰ and indicate involvement of a low‐18O component in their source magmas. Hrafnsfjörður zircon Hf (mean sample
ε Hf∼ +15.3–16.0) and whole rock Hf and Nd (ε Hf = +14.5 to +15;ε Nd = +7.9 to +8.1) isotopic compositions are more radiogenic than those from Árnes (zircon sampleε Hf∼ +11.8–13; whole rockε Hf = +12.8 to +15.1;ε Nd = +7.3 to +7.7), but Hrafnsfjörður whole rock Pb isotope compositions (208/204Pb = 37.95–37.96;206/204Pb = 18.33–18.35) are less radiogenic than those from Árnes (208/204Pb = 38.34–38.48;206/204Pb = 18.64–18.78). Kaldalón has zircon Hf isotope compositions ofε Hf∼+14.8 and 15.5 (sample means). These age and isotopic differences suggest that interaction of rift and plume, and thus the geodynamic evolution of the Westfjords, is complex. Isotopic compositions of Hrafnsfjörður and Árnes support involvement of an enriched mantle (EM)‐like mantle component associated with a pulsing plume that resulted in variable spreading rates and magma fluxes and highlight the heterogeneity of the Icelandic mantle. -
null (Ed.)Abstract Recovering the time-evolving relationship between arc magmatism and deformation, and the influence of anisotropies (inherited foliations, crustal-scale features, and thermal gradients), is critical for interpreting the location, timing, and geometry of transpressional structures in continental arcs. We investigated these themes of magma-deformation interactions and preexisting anisotropies within a middle- and lower-crustal section of Cretaceous arc crust coinciding with a Paleozoic boundary in central Fiordland, New Zealand. We present new structural mapping and results of Zr-in-titanite thermometry and U-Pb zircon and titanite geochronology from an Early Cretaceous batholith and its host rock. The data reveal how the expression of transpression in the middle and lower crust of a continental magmatic arc evolved during emplacement and crystallization of the ∼2300 km2 lower-crustal Western Fiordland Orthogneiss (WFO) batholith. Two structures within Fiordland’s architecture of transpressional shear zones are identified. The gently dipping Misty shear zone records syn-magmatic oblique-sinistral thrust motion between ca. 123 and ca. 118 Ma, along the lower-crustal WFO Misty Pluton margin. The subhorizontal South Adams Burn thrust records mid-crustal arc-normal shortening between ca. 114 and ca. 111 Ma. Both structures are localized within and reactivate a recently described >10 km-wide Paleozoic crustal boundary, and show that deformation migrated upwards between ca. 118 and ca. 114 Ma. WFO emplacement and crystallization (mainly 118–115 Ma) coincided with elevated (>750 °C) middle- and lower-crustal Zr-in-titanite temperatures and the onset of mid-crustal cooling at 5.9 ± 2.0 °C Ma−1 between ca. 118 and ca. 95 Ma. We suggest that reduced strength contrasts across lower-crustal pluton margins during crystallization caused deformation to migrate upwards into thermally weakened rocks of the mid-crust. The migration was accompanied by partitioning of deformation into domains of arc-normal shortening in Paleozoic metasedimentary rocks and domains that combined shortening and strike-slip deformation in crustal-scale subvertical, transpressional shear zones previously documented in Fiordland. U-Pb titanite dates indicate Carboniferous–Cretaceous (re)crystallization, consistent with reactivation of the inherited boundary. Our results show that spatio-temporal patterns of transpression are influenced by magma emplacement and crystallization and by the thermal structure of a reactivated boundary.more » « less
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Abstract We investigated the interplay between deformation and pluton emplacement with the goal of providing insights into the role of transpression and arc magmatism in forming and modifying continental arc crust. We present 39 new laser-ablation–split-stream–inductively coupled plasma–mass spectrometry (LASS-ICP-MS) and secondary ion mass spectrometry (SIMS) 206Pb/238U zircon and titanite dates, together with titanite geochemistry and temperatures from the lower and middle crust of the Mesozoic Median Batholith, New Zealand, to (1) constrain the timing of Cretaceous arc magmatism in the Separation Point Suite, (2) document the timing of titanite growth in low- and high-strain deformational fabrics, and (3) link spatial and temporal patterns of lithospheric-scale transpressional shear zone development to the Cretaceous arc flare-up event. Our zircon results reveal that Separation Point Suite plutonism lasted from ca. 129 Ma to ca. 110 Ma in the middle crust of eastern and central Fiordland. Deformation during this time was focused into a 20-km-wide, arc-parallel zone of deformation that includes previously unreported segments of a complex shear zone that we term the Grebe shear zone. Early deformation in the Grebe shear zone involved development of low-strain fabrics with shallowly plunging mineral stretching lineations from ca. 129 to 125 Ma. Titanites in these rocks are euhedral, are generally aligned with weak subsolidus fabrics, and give rock-average temperatures ranging from 675 °C to 700 °C. We interpret them as relict magmatic titanites that grew prior to low-strain fabric development. In contrast, deformation from ca. 125 to 116 Ma involved movement along subvertical, mylonitic shear zones with moderately to steeply plunging mineral stretching lineations. Titanites in these shear zones are anhedral grains/aggregates that are aligned within mylonitic fabrics and have rock-average temperatures ranging from ∼610 °C to 700 °C. These titanites are most consistent with (re)crystallization in response to deformation and/or metamorphic reactions during amphibolite-facies metamorphism. At the orogen scale, spatial and temporal patterns indicate that the Separation Point Suite flare-up commenced during low-strain deformation in the middle crust (ca. 129–125 Ma) and peaked during high-strain, transpressional deformation (ca. 125–116 Ma), during which time the magmatic arc axis widened to 70 km or more. We suggest that transpressional deformation during the arc flare-up event was an important process in linking melt storage regions and controlling the distribution and geometry of plutons at mid-crustal levels.more » « less