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We analyzed the surface of a freshly exfoliated single crystal of zirconium(IV) sulfide, ZrS2. Survey spectra and high-resolution spectra from the core levels Zr 4p, Zr 4s, Zr 3d, Zr 3p, Zr 3s, S 2p, S 2s, O 1s, and C 1s were acquired. The binding energies and peak area ratios of a stoichiometric ZrS2 single crystal provide a pure reference of well-defined composition for material deposited by chemical or physical vapor deposition methods.more » « lessFree, publicly-accessible full text available June 1, 2026
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Many microelectronic devices require thin films of silver or gold as wiring layers. We report silver( i ) and gold( i ) bicyclic amidinate complexes, wherein the constrained ligand geometry lessens the propensity for thermal decomposition. These new volatile compounds provide metallic films of silver and gold during CVD with hydrogen below 230 °C.more » « less