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  1. The effects of surfactants on a mechanically generated plunging breaker are studied experimentally in a laboratory wave tank. Waves are generated using a dispersively focused wave packet with a characteristic wavelength of$$\lambda _0 = 1.18$$m. Experiments are performed with two sets of surfactant solutions. In the first set, increasing amounts of the soluble surfactant Triton X-100 are mixed into the tank water, while in the second set filtered tap water is left undisturbed in the tank for wait times ranging from 15 min to 21 h. Increasing Triton X-100 concentrations and longer wait times lead to surfactant-induced changes in the dynamic properties of the free surface in the tank. It is found that low surface concentrations of surfactants can dramatically change the wave breaking process by changing the shape of the jet and breaking up the entrained air cavity at the time of jet impact. Direct numerical simulations (DNS) of plunging breakers with constant surface tension are used to show that there is significant compression of the free surface near the plunging jet tip and dilatation elsewhere. To explore the effect of this compression/dilatation, the surface tension isotherm is measured in all experimental cases. The effects of surfactants on the plunging jet are shown to be primarily controlled by the surface tension gradient ($$\Delta \mathcal {E}$$) while the ambient surface tension of the undisturbed wave tank ($$\sigma _0$$) plays a secondary role. 
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  2. We present high-resolution three-dimensional (3-D) direct numerical simulations of breaking waves solving for the two-phase Navier–Stokes equations. We investigate the role of the Reynolds number ( Re , wave inertia relative to viscous effects) and Bond number ( Bo , wave scale over the capillary length) on the energy, bubble and droplet statistics of strong plunging breakers. We explore the asymptotic regimes at high Re and Bo , and compare with laboratory breaking waves. Energetically, the breaking wave transitions from laminar to 3-D turbulent flow on a time scale that depends on the turbulent Re up to a limiting value $$Re_\lambda \sim 100$$ , consistent with the mixing transition in other canonical turbulent flows. We characterize the role of capillary effects on the impacting jet and ingested main cavity shape and subsequent fragmentation process, and extend the buoyant-energetic scaling from Deike et al. ( J. Fluid Mech. , vol. 801, 2016, pp. 91–129) to account for the cavity shape and its scale separation from the Hinze scale, $$r_H$$ . We confirm two regimes in the bubble size distribution, $$N(r/r_H)\propto (r/r_H)^{-10/3}$$ for $$r>r_H$$ , and $$\propto (r/r_H)^{-3/2}$$ for $$r 
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  3. Air bubbles at the surface of water end their life in a particular way: when bursting, they may eject drops of liquid in the surrounding environment. Many uncertainties remain regarding collective effects of bubbles at the water–air interface, despite extensive efforts to describe the bursting mechanisms, motivated by their critical importance in mass transfers between the ocean and the atmosphere in the production of sea spray aerosols. We investigate the effect of surfactant on the collective dynamics and statistics of air bubbles evolving freely at the surface of water, through an experimental set-up controlling the bulk distribution of bubbles with nearly monodisperse millimetric air bubbles. We observe that for low contamination, bubble coalescence is inevitable and leads to a broad surface size distribution. For higher surfactant concentrations, coalescence at the surface is prevented and bubble lifetime is increased, leading to the formation of rafts with a surface size distribution identical to the bulk distribution. This shows that surface contamination has a first-order influence on the transfer function from bulk size distribution to surface size distribution, an intermediate step which needs to be considered when developing sea spray source function as droplet production by bubble bursting depends on the bubble size. We measure the bursting and merging rates of bubbles as a function of contamination through a complementary freely decaying raft experiment. We propose a cellular automaton model that includes the minimal ingredients to reproduce the experimental results in the statistically stationary configuration: production, coalescence and bursting after a finite lifetime. 
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