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Creators/Authors contains: "Delano_IV, Francis"

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  1. An unprecedented dinuclear rare earth metal complex with a bridging 2,2'-azobispyridyl radical anion was isolated from the one-electron oxidation of the parent neutral complex. Both were characterized through crystallography, spectroscopy, and DFT. 
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  2. The first complexes containing a 2,3,4,5-tetraiodopyrrolyl anion as a ligand were isolated. The ligands' tendency to foster intermolecular σ-hole interactions was probed and compared to rare earth metal complexes bearing a 2,5-dimethylpyrrolyl anion. 
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