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The 2011–2012 eruption at Cordón Caulle, Chile offers an exceptional opportunity to investigate topographic evolution of a laccolith, lava flows, and tephra during and after rhyolitic eruptions using satellite TanDEM-X and Plèiades data. We find distinct phases: rapid surface uplift from the laccolith and tephra (June–August 2011) and lava (June 2011–March 2012), followed by a reduction in the elevation of the laccolith and tephra (up to 19 m yr−1) until February 2013, and slower subsidence of all deposits until 2019 (the most recent data). The spatial distribution of subsidence-to-uplift ratios shows different volcanic and geomorphological processes occurring (degassing, cooling, crystallization, lateral movement, compaction, erosion). Pre-eruptive river channels showed elevation increases of up to 10–50 m due to tephra deposition, but this tephra was largely removed within three to four years. This research shows the potential of repeating high-resolution remote sensing elevation data to elucidate volcanic landscape evolution and yields insights into the co- and post-eruptive evolution of deposits. 

SUMMARY The 2011–2012 eruption at Cordón Caulle in Chile produced crystal-poor rhyolitic magma with crystal-rich mafic enclaves whose interstitial glass is of identical composition to the host rhyolite. Eruptible rhyolites are thought to be genetically associated with crystal-rich magma mushes, and the enclaves within the Cordón Caulle rhyolite support the existence of a magma mush from which the erupted magma was derived. Moreover, towards the end of the 2011–2012 eruption, subsidence gave way to inflation that has on average been continuous through at least 2020. We hypothesize that magma segregation from a crystal mush could be the source of the observed inflation. Conceptually, magma withdrawal from a crystal-poor rhyolite reservoir caused its depressurization, which could have led to upward flow of interstitial melt within an underlying crystal mush, causing a new batch of magma to segregate and partially recharge the crystal-poor rhyolite body. Because the compressibility of the crystalline matrix of the mush is expected to be lower than that of the interstitial melt, which likely contains some fraction of volatile bubbles, this redistribution of melt would result in a net increase in volume of the system and in the observed inflation. We use numerical modelling of subsurface magma flow and storage to show under which conditions such a scenario is supported by geodetic and petrologic observations. 

Abstract Two distinct types of rare crystal-rich mafic enclaves have been identified in the rhyolite lava flow from the 2011–12 Cordón Caulle eruption (Southern Andean Volcanic Zone, SVZ). The majority of mafic enclaves are coarsely crystalline with interlocking olivine-clinopyroxene-plagioclase textures and irregular shaped vesicles filling the crystal framework. These enclaves are interpreted as pieces of crystal-rich magma mush underlying a crystal-poor rhyolitic magma body that has fed recent silicic eruptions at Cordón Caulle. A second type of porphyritic enclaves, with restricted mineral chemistry and spherical vesicles, represents small-volume injections into the rhyolite magma. Both types of enclaves are basaltic end-members (up to 9.3 wt% MgO and 50–53 wt% SiO 2 ) in comparison to enclaves erupted globally. The Cordón Caulle enclaves also have one of the largest compositional gaps on record between the basaltic enclaves and the rhyolite host at 17 wt% SiO 2 . Interstitial melt in the coarsely-crystalline enclaves is compositionally identical to their rhyolitic host, suggesting that the crystal-poor rhyolite magma was derived directly from the underlying basaltic magma mush through efficient melt extraction. We suggest the 2011–12 rhyolitic eruption was generated from a primitive basaltic crystal-rich mush that short-circuited the typical full range of magmatic differentiation in a single step. 

Abstract This work reports on the correlation between structure, surface/interface morphology and mechanical properties of pulsed laser deposited (PLD)β-Ga₂O₃films on transparent quartz substrates. By varying the deposition temperature in the range of 25 °C–700 °C, ∼200 nm thick Ga₂O₃films with variable microstructure and amorphous-to-nanocrystalline nature were produced onto quartz substrates by PLD. The Ga₂O₃films deposited at room temperature were amorphous; nanocrystalline Ga₂O₃films were realized at 700 °C. The interface microstructure is characterized with a typical nano-columnar morphology while the surface exhibits the uniform granular morphology. Corroborating with structure and surface/interface morphology, and with increasing deposition temperature, tunable mechanical properties were seen in PLD Ga₂O₃films. At 700 °C, for nanocrystalline Ga₂O₃films, the dense grain packing reduces the elastic modulus E_rwhile improving the hardness. The improved crystallinity at elevated temperatures coupled with nanocrystallinity, theβ-phase stabilization is accounted for the observed enhancement in the mechanical properties of PLD Ga₂O₃films. The structure-morphology-mechanical property correlation in nanocrystalline PLDβ-Ga₂O₃films deposited on quartz substrates is discussed in detail. 

ABSTRACT The ability to interface electronic materials with the peripheral nervous system is required for stimulation and monitoring of neural signals. Thus, the design and engineering of robust neural interfaces that maintain material-tissue contact in the presence of material or tissue micromotion offer the potential to conduct novel measurements and develop future therapies that require chronic interface with the peripheral nervous system. However, such remains an open challenge given the constraints of existing materials sets and manufacturing approaches for design and fabrication of neural interfaces. Here, we investigated the potential to leverage a rapid prototyping approach for the design and fabrication of nerve cuffs that contain supporting features to mechanically stabilize the interaction between cuff electrodes and peripheral nerve. A hybrid 3D printing and robotic-embedding (i.e., pick-and-place) system was used to design and fabricate silicone nerve cuffs (800 µm diameter) containing conforming platinum (Pt) electrodes. We demonstrate that the electrical impedance of the cuff electrodes can be reduced by deposition of the conducting polymer poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) on cuff electrodes via a post-processing electropolymerization technique. The computer-aided design and manufacturing approach was also used to design and integrate supporting features to the cuff that mechanically stabilize the interface between the cuff electrodes and the peripheral nerve. Both ‘self-locking’ and suture-assisted locking mechanisms are demonstrated based on the principle of making geometric alterations to the cuff opening via 3D printing. Ultimately, this work shows 3D printing offers considerable opportunity to integrate supporting features, and potentially even novel electronic materials, into nerve cuffs that can support the design and engineering of next generation neural interfaces.