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We report results of magnetization and 19F NMR measurements in the normal state of as-grown vacuum-annealed LaO0.5β’F0.5β‘BiS2. The magnetization is dominated by a temperature-independent diamagnetic component and a field- and temperature-dependent paramagnetic contribution ππβ‘(π»,π) from a βΌ1000 ppm concentration of local moments, an order of magnitude higher than can be accounted for by measured rare-earth impurity concentrations. ππβ‘(π»,π) can be fit by the Brillouin function π΅π½β‘(π₯) or, perhaps more realistically, a two-level tanhβ‘(π₯) model for magnetic Bi 6β’π ions in defect crystal fields. Both fits require a phenomenological Curie-Weiss argument π₯=πeffβ’π»β‘/(π+ππ), ππβ1.7 K. There is no evidence for magnetic order down to 2 K, and the origin of ππ is not clear. 19F frequency shifts, linewidths, and spin-lattice relaxation rates are consistent with purely dipolar 19F/defect-spin interactions. The defect-spin correlation time ππβ‘(π) obtained from 19F spin-lattice relaxation rates obeys the Korringa relation ππβ’π=const, indicating the relaxation is dominated by conduction-band fluctuations.more » « less
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