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Abstract During Big Bang nucleosynthesis (BBN) in the first 15 minutes of the Universe, some⁷Li was created along with isotopes of H and He. The determination of that primordial value of Li can help constrain the conditions at that time. The oldest stars with known ages can be found in globular clusters which have well-determined ages through stellar evolution models. High-resolution spectra of Li have been obtained with the Keck I Telescope and HIRES in several unevolved stars in the clusters M13 and M71 withVmagnitudes of 17.6–17.9. Abundances of Li have been determined with spectrum synthesis techniques and show a range of a factor of 4. We attribute that spread to differences in initial angular momentum resulting in different amounts of spin-down, related mixing, and destruction of Li. Our results are compared with similar results for main-sequence and turnoff stars in other globular clusters. The range in age of these clusters is 11.2–14.2 Gyr for an age span of 3 Gyr. These clusters range in [Fe/H] from −0.75 to −2.24 corresponding to a factor of 30 in metallicity. The maximum in the Li abundance for these unevolved stars in all eight clusters is the same corresponding to Li/H = 3.16 × 10⁻¹⁰, while the predicted Li abundance, based on the deuterium abundance and the BBN predictions, is 5.24 × 10⁻¹⁰. 

Abstract We have analyzed high-dispersion spectra in the Li 6708 Å region for 167 stars within the anticenter cluster NGC 2204. From 105 probable members, abundance analysis of 45 evolved stars produces [Fe/H] = −0.40 ± 0.12, [Si/Fe] = 0.14 ± 0.12, [Ca/Fe] = 0.29 ± 0.07, and [Ni/Fe] = −0.12 ± 0.10, where quoted errors are standard deviations. WithE(B−V) = 0.07 and (m−M)₀= 13.12, appropriate isochrones provide an excellent match from the main sequence through the tip of the giant branch for an age of 1.85 ± 0.05 Gyr. Li spectrum synthesis producesA(Li) below 1.4 at the base of the red giant branch to a detectable value of −0.4 at the tip. Six probable asymptotic giant branch stars and all but one red clump star have only Li upper limits. A rapidly rotating red giant is identified as a possible Li-rich giant, assuming it is a red clump star. Main-sequence turnoff stars have a well-definedA(Li) = 2.83 ± 0.03 (sem) down to the Li-dip wall at the predicted mass of 1.29M_☉. Despite having the same isochronal age as the more metal-rich NGC 2506, the luminosity distribution of red giants reflects a younger morphology similar to NGC 7789, possibly indicating a deeper impact of metallicity on stellar structure andA(Li) than previously assumed. As in NGC 2506 and NGC 7789, the NGC 2204 turnoff exhibits a broad range of rotation speeds, making abundance estimation impossible for some stars. The place of the cluster within GalacticA(Li) evolution is discussed.