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Creators/Authors contains: "Droege, Daniel G."

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  1. ; ; ; ; ; (, Crystal Growth & Design)
    Free, publicly-accessible full text available October 2, 2025
  2. ; ; ; ; (, Inorganic Chemistry)
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  3. ; (, Chemical Communications)
    We describe herein a small-molecule platform that exhibits key properties needed by an antidote for CO poisoning. The design features an iron-porphyrin complex with bulky substituents above and below the macrocyclic plane to provide a hydrophobic pocket for CO binding and to prevent the formation of inactive oxo-bridged dimers. Peripheral charged groups impart water solubility. We demonstrate that the Fe( ii ) complex of a porphyrin with 2,6-diphenyl-4-sulfophenyl meso substituents can bind CO, stoichiometrically sequester CO from carboxyhemoglobin, and rescue CO-poisoned red blood cells. 
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  4. ; ; ; ; (, The Journal of Organic Chemistry)