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Ma, Pengchen; Svatunek, Dennis; Zhu, Zixi; Boger, Dale L; Duan, Xin-Hua; Houk, K N (, Journal of the American Chemical Society)
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Liu, Shuai; Ma, Pengchen; Zhang, Lu; Shen, Shenyu; Miao, Hong-Jie; Liu, Le; Houk, K. N.; Duan, Xin-Hua; Guo, Li-Na (, Chemical Science)A Cu or Fe-catalyzed radical ring expansion/coupling cascade was developed. It provides a new access to medium-sized and macrolactones with CN, N3, SCN, and X groups. DFT calculations suggest a Cu(i)/Cu(ii)/Cu(iii) catalytic cycle for the cyanation.more » « less
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