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Wide bandgap (WBG) and ultra-wide bandgap (UWBG)-based inverters are increasingly being adopted in More Electric Aircraft (MEA) and All Electric Aircraft (AEA) due to their ability to operate at higher switching frequencies with improved efficiency and power density. However, these advantages come with drawbacks, including increased electrical stress and exacerbation of AC losses, such as the skin effect and proximity effect. Litz wire, known for its effectiveness in mitigating these losses, is becoming a preferred conductor in highvoltage, high-frequency aerospace applications. This study investigates the breakdown voltage behavior of Litz wire insulation under square wave voltage stress across different frequencies. Twisted-pair Litz wire specimens were tested using a state-of-the-art high-voltage pulse generator with fixed rise times to emulate inverter-fed conditions. The resulting breakdown voltages were statistically analyzed using the Weibull distribution to evaluate insulation strength and failure predictability. The findings offer new insights into the insulation characteristics of Litz wire under realistic high-frequency converter stress and support the development of converter-resistant insulation systems for next-generation aerospace electrical power systems (EPS).