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Math performance continues to be an important focus for improve- ment. Many districts adopted educational technology programs to support student learning and teacher instruction. The ASSISTments program provides feedback to students as they solve homework problems and automatically prepares reports for teachers about student performance on daily assignments. During the 2018- 19 and 2019-20 school years, we conducted a large-scale randomized controlled trial to replicate the effects of ASSISTments in 63 schools in North Carolina in the US. 32 treatment schools implemented ASSISTments in 7th-grade math class- rooms. Recently, we conducted a follow-up analysis to measure the long-term effects of ASSISTments on student performance one year after the intervention, when the students were in 8th grade. The initial results suggested that implement- ing ASSISTments in 7th grade improved students’ performance in 8th grade and minority students benefited more from the intervention. 

Destruction of pharmaceuticals excreted in urine can be an efficient approach to eliminate these environmental pollutants. However, urine contains high concentrations of chloride, ammonium, and bicarbonate, which may hinder treatment processes. This study evaluated the application of ferrate(VI) (FeVIO42-, Fe(VI)) to oxidize pharmaceuticals (carbamazepine (CBZ), naproxen (NAP), trimethoprim (TMP) and sulfonamide antibiotics (SAs)) in synthetic hydrolyzed human urine and uncovered new effects from urine’s major inorganic constituents. Chloride slightly decreased pharmaceuticals’ removal rate by Fe(VI) due to the ionic strength effect. Ammonium (0.5 M) in undiluted hydrolyzed urine posed a strong scavenging effect, but lower concentrations (≤ 0.25 M) of ammonium enhanced the pharmaceuticals’ degradation by 300 µM Fe(VI), likely due to the reactive ammonium complex form of Fe(V)/Fe(IV). For the first time, bicarbonate was found to significantly promote the oxidation of aniline-containing SAs by Fe(VI) and alter the reaction stoichiometry of Fe(VI) and SA from 4:1 to 3:1. In-depth investigation indicated that bicarbonate not only changed the Fe(VI):SA complexation ratio from 1:2 to 1:1, but provided stabilizing effect for Fe(V) intermediate formed in situ, enabling its degradation of SAs. Overall, results of this study suggested that Fe(VI) is a promising oxidant for the removal of pharmaceuticals in hydrolyzed urine. 

An extruded AZ31B (Mg-3Al-1Zn-0.5Mn) magnesium alloy with a twin volume fraction of 60% was subjected to fully reversed strain-controlled tension-compression along the extrusion direction at strain amplitudes ranging from 0.23% to 0.45%. Dislocation slips were the dominant plastic deformation mechanisms without involving persistent twinning-detwinning. At an identical strain amplitude, the fatigue life of the pre-twinned alloy was much lower than that of the as-extruded alloy. Fatigue cracks were mainly initiated on the prismatic or prismatic-basal slip bands in the parent grains. The material volume reduction of the parent grains in the pre-twinned alloy enhanced fatigue damage. Twin cracks were not observed. 

A search for hidden-charm pentaquark states decaying to a range of${\mathrm{\Sigma }}_c\overline{D}$and${\mathrm{\Lambda }}_c^{+}\overline{D}$final states, as well as doubly charmed pentaquark states to${\mathrm{\Sigma }}_{c}D$and${\mathrm{\Lambda }}_c^{+}D$, is made using samples of proton-proton collision data corresponding to an integrated luminosity of$5.7{\mathrm{fb}}^{-1}$recorded by the LHCb detector at$\sqrt{s}=13\mathrm{TeV}$. Since no significant signals are found, upper limits are set on the pentaquark yields relative to that of the${\mathrm{\Lambda }}_c^{+}$baryon in the${\mathrm{\Lambda }}_c^{+}\to p{K}^{-}{\pi }^{+}$decay mode. The known pentaquark states are also investigated, and their signal yields are found to be consistent with zero in all cases.

© 2024 CERN, for the LHCb Collaboration2024CERN 

This paper presents ferrate(VI) (FeVIO42-, FeVI) oxidation of a wide range of sulfonamide antibiotics (SAs) containing five- and six-membered heterocyclic moieties (R) in their molecular structures. Kinetics measurements of the reactions between FeVI and SAs at different pH (6.5 – 10.0) give species-specific second-order rate constants, k5 and k6 of the reactions of protonated FeVI (HFeO4-) and unprotonated FeVI (FeVIO42-) with protonated SAs (HX), respectively. The values of k5 varied from (1.2 ± 0.1) × 103 to (2.2 ± 0.2) × 104 M-1 s-1, while the range of k6 was from (1.1 ± 0.1) × 102 to (1.0 ± 0.1) × 103 M-1 s-1 for different SAs. The transformation products of reaction between FeVI and sulfadiazine (SDZ, contains a six-membered R) include SO2 extrusion oxidized products (OPs) and aniline hydroxylated products. Comparatively, oxidation of sulfisoxazole (SIZ, a five-membered R) by FeVI has OPs that have no SO2 extrusion in their structures. Density functional theory (DFT) calculations are performed to demonstrate SO2 extrusion in oxidation of SDZ by FeVI. The detailed mechanisms of oxidation are proposed to describe the differences in the oxidation of six- and five-membered heterocyclic moieties (R) containing SAs (i.e., SDZ versus SIZ) by FeVI. 

The electrically pumped vertical-cavity surface- emitting laser (VCSEL) was first demonstrated with metal cavities by Iga (1979); however, the device threshold current was too high. Distributed Bragg reflector cavities proposed by Scifres and Burnham (1975) were adopted to improve the optical cavity loss. Yet, it was not a practical use until the discovery of the native oxide of AlGaAs and the insertion of quantum wells to provide simultaneous current and optical confinement in semiconductor laser by Holonyak and Dallesasse (1990). Later, the first “low- threshold” oxide-confined VCSEL was realized by Deppe (1994) and opened the door of commercial application for a gigabit energy-efficient optical links. At present, we demonstrated that the oxide-confined VCSELs have advanced error-free data trans- mission [bit-error rate (BER) ≤ 10−12]to 57 Gb/s at 25 °C and 50 Gb/s at 85 °C, and also demonstrated that the pre-leveled 16-quadrature amplitude modulation orthogonal frequency- division multiplexing data were achieved at 104 Gbit/s under back-to-back transmission with the received error vector mag- nitude, SNR, and BER of 17.3%, 15.2 dB, and 3.8 × 10−3, respectively. 

A search for the fully reconstructed$$ {B}_s^0 $$$B_s^0$→ μ⁺μ⁻γdecay is performed at the LHCb experiment using proton-proton collisions at$$ \sqrt{s} $$$\sqrt{s}$= 13 TeV corresponding to an integrated luminosity of 5.4 fb⁻¹. No significant signal is found and upper limits on the branching fraction in intervals of the dimuon mass are set$$ {\displaystyle \begin{array}{cc}\mathcal{B}\left({B}_s^0\to {\mu}^{+}{\mu}^{-}\gamma \right)<4.2\times {10}^{-8},& m\left({\mu}^{+}{\mu}^{-}\right)\in \left[2{m}_{\mu },1.70\right]\textrm{GeV}/{c}^2,\\ {}\mathcal{B}\left({B}_s^0\to {\mu}^{+}{\mu}^{-}\gamma \right)<7.7\times {10}^{-8},&\ m\left({\mu}^{+}{\mu}^{-}\right)\in \left[\textrm{1.70,2.88}\right]\textrm{GeV}/{c}^2,\\ {}\mathcal{B}\left({B}_s^0\to {\mu}^{+}{\mu}^{-}\gamma \right)<4.2\times {10}^{-8},& m\left({\mu}^{+}{\mu}^{-}\right)\in \left[3.92,{m}_{B_s^0}\right]\textrm{GeV}/{c}^2,\end{array}} $$$\begin{array}{cc}B\left(B_s^0\to {\mu }^{+}{\mu }^{-}\gamma \right)<4.2\times {10}^{-8},& m\left({\mu }^{+}{\mu }^{-}\right)\in \left(2m_{\mu },1.70\right)\mathrm{GeV}/c^2,\\ B\left(B_s^0\to {\mu }^{+}{\mu }^{-}\gamma \right)<7.7\times {10}^{-8},& m\left({\mu }^{+}{\mu }^{-}\right)\in \left(\mathrm{1.70,\; 2.88}\right)\mathrm{GeV}/c^2,\\ B\left(B_s^0\to {\mu }^{+}{\mu }^{-}\gamma \right)<4.2\times {10}^{-8},& m\left({\mu }^{+}{\mu }^{-}\right)\in \left(3.92,m_{B_s^0}\right)\mathrm{GeV}/c^2,\end{array}$

at 95% confidence level. Additionally, upper limits are set on the branching fraction in the [2m_μ,1.70] GeV/c²dimuon mass region excluding the contribution from the intermediateϕ(1020) meson, and in the region combining all dimuon-mass intervals.

 

A search for the nonresonant production of Higgs boson pairs in the$HH\to b\overline{b}{\tau }^{+}{\tau }^{-}$channel is performed using$140{\mathrm{fb}}^{-1}$of proton-proton collisions at a center-of-mass energy of 13 TeV recorded by the ATLAS detector at the CERN Large Hadron Collider. The analysis strategy is optimized to probe anomalous values of the Higgs boson self-coupling modifier${\kappa }_{\lambda }$and of the quartic$HHVV$($V=W,Z$) coupling modifier${\kappa }_{2V}$. No significant excess above the expected background from Standard Model processes is observed. An observed (expected) upper limit${\mu }_{HH}<5.9(3.3)$is set at 95% confidence-level on the Higgs boson pair production cross section normalized to its Standard Model prediction. The coupling modifiers are constrained to an observed (expected) 95% confidence interval of$-3.1<{\kappa }_{\lambda }<9.0$($-2.5<{\kappa }_{\lambda }<9.3$) and$-0.5<{\kappa }_{2V}<2.7$($-0.2<{\kappa }_{2V}<2.4$), assuming all other Higgs boson couplings are fixed to the Standard Model prediction. The results are also interpreted in the context of effective field theories via constraints on anomalous Higgs boson couplings and Higgs boson pair production cross sections assuming different kinematic benchmark scenarios.

© 2024 CERN, for the ATLAS Collaboration2024CERN