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When imaging underwater scenes from above the water surface, the reflection from the air–water interface creates an obscuring background that varies with illumination and viewing angles. It is well known that the reflected light is horizontally polarized, and using a vertically transmitting polarizing filter is a common technique to improve the contrast of underwater scenes. However, to our knowledge, no quantitative measurements of polarization-enabled contrast enhancement have been reported in the literature. In this work, panchromatic and RGB division-of-focal-plane polarization cameras were used to record images of black and white tiles submerged in water for determining contrast as a function of viewing angle, both without a polarizer and with a vertical polarizer. Experiments were conducted in two outdoor locations and in a black tub indoors with controlled color and brightness of the reflected background. The maximum contrast through a vertical polarizer occurred near the Brewster angle, but the amount of contrast enhancement (the ratio of contrast through a polarizer to contrast without a polarizer) was found to increase until much larger angles. Also, the observed changes in contrast resulting from changing properties of the reflected background were consistent with the Fresnel reflection coefficients.