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Photonic materials with a prescribed response over multiple spectral bands are essential to applications such as energy harvesting and thermal management. Engineering the response over such a wide range of wavelengths is difficult because these materials have hierarchical structures, which make it challenging to predict and optimize the spectral response. To address this challenge, we develop and compare several optical models aimed at capturing multiscale effects, and we apply these models to understanding the response of microgeodes—dielectric microshells encapsulating nanowires. Among the models, we find that an intensity-based transfer matrix method, newly developed in this work, provides the best agreement with experimentally observed spectra. In particular, it substantially improves the prediction of reflectance at short wavelengths, where the other models significantly underestimate the experimental values, resulting in an overall improvement across the full spectrum. We show that this model has superior predictive performance because it accounts for the interdependent scattering contributions from nanowires and microshells, while circumventing the need to specify reflectance conditions at the boundaries of the microgeode film. This approach could be used to explore the large design space of possible structures in microgeodes and other hierarchically structured, broad-spectrum materials. 

Micro- or nano-diodes suspended in water can propel controllably under alternating-current fields or light without the need for fuels such as hydrogen peroxide or urea. This makes them promising candidates for miniature motors in biomedical and other applications. However, the mechanisms underlying their propulsion remain unclear. This study investigates the propulsion of diodes floating in an aqueous solution at the millimeter scale, which facilitates observation of motion, allowing direct correlation with electrical measurements of device properties. We find that the diode’s propulsion is driven by forward current under an alternating-current field and by photocurrent under illumination. The velocity of propulsion scales linearly with the net current, with the rectified or photogenerated current creating an imbalance of ions at the ends of the diodes. This, in turn, generates an electric field that induces electrophoretic flow around the diode and propels the diode. Additionally, we assess the velocity of diodes intentionally damaged by high reverse bias and find that it decreases significantly because of the reduced difference between forward and reverse currents. These results suggest potential uses of diode propulsion for characterizing and separating bottom-up-grown nano-/micro- diodes based on their reverse-saturation current, as well as nanomotors formed from multiple-junction nanowire diodes that can self-propel in water under light. 

Self-aligned metal-oxide-semiconductor (MOS) capacitors are studied with several low-temperature, wet chemical silicon dioxide (SiO2) interlayers to understand their impact on electrical performance. Self-aligned MOS capacitors are fabricated with a bottom-up patterning technique that uses a poly(methyl methacrylate) brush and dopant-selective KOH etch combined with area-selective atomic layer deposition of hafnium dioxide (HfO2) and Pt. The wet chemical pretreatments used to form the SiO2 interlayer include hydrofluoric acid (HF) etch, 80 °C H2O, and SC-2. Capacitance-voltage measurements of these area-selective capacitors exhibit a HfO2 dielectric constant of ∼19, irrespective of pretreatment. After a forming gas anneal, the average interface state density decreased between 1.8 and 7.5 times. The minimum observed Dit is 1 × 1011 eV−1 cm−2 for the HF-last treatment. X-ray photoelectron spectroscopy shows an increase in stoichiometric SiO2 in the interfacial layer after the anneal. Additional carbon is also observed; however, comparison with capacitors fabricated in a nonselective process reveals minimal impact on performance. 

Doped semiconductor nanowires are emerging as next-generation electronic colloidal materials, and the efficient manipulation of such nanostructures is crucial for technological applications. In fluid suspension, pn nanowires (pn NWs), unlike homogeneous nanowires, have a permanent dipole, and thus, experience a torque under an external DC field that orients the nanowire with its n-type end in the direction of the field. Here, we quantitatively measure the permanent dipoles of various Si nanowire pn diodes and investigate their origin. By comparing the dipoles of pn NWs of different lengths and radii, we show that the permanent dipole originates from non-uniform surface-charge distributions, rather than the internal charges at the p–n junction as was previously proposed. This understanding of the mechanism for pn NWs orientation has relevance to the manipulation, assembly, characterization, and separation of nanowire electronics by electric fields. 

Abstract We demonstrate a bottom-up process for programming the deposition of coaxial thin films aligned to the underlying dopant profile of semiconductor nanowires. Our process synergistically combines three distinct methods—vapor–liquid–solid nanowire growth, selective coaxial lithography via etching of surfaces (SCALES), and area-selective atomic layer deposition (AS-ALD)—into a cohesive whole. Here, we study ZrO 2 on Si nanowires as a model system. Si nanowires are first grown with an axially modulated n-Si/i-Si dopant profile. SCALES then yields coaxial poly(methyl methacrylate) (PMMA) masks on the n-Si regions. Subsequent AS-ALD of ZrO 2 occurs on the exposed i-Si regions and not on those masked by PMMA. We show the spatial relationship between nanowire dopant profile, PMMA masks, and ZrO 2 films, confirming the programmability of the process. The nanoscale resolution of our process coupled with the plethora of available AS-ALD chemistries promises a range of future opportunities to generate structurally complex nanoscale materials and electronic devices using entirely bottom-up methods.