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Abstract. Short-lived highly reactive atmospheric species, such as organic peroxy radicals (RO2) and stabilized Criegee intermediates (SCIs), play an important role in controlling the oxidative removal and transformation of many natural and anthropogenic trace gases in the atmosphere. Direct speciated measurements of these components are extremely helpful for understanding their atmospheric fate and impact. We describe thedevelopment of an online method for measurements of SCIs and RO2 inlaboratory experiments using chemical derivatization and spin trappingtechniques combined with H3O+ and NH4+ chemicalionization mass spectrometry (CIMS). Using chemical derivatization agentswith low proton affinity, such as electron-poor carbonyls, we scavenge allSCIs produced frommore »
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Free, publicly-accessible full text available September 1, 2022
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Abstract. Oxidation of organic compounds in the atmosphere produces an immenselycomplex mixture of product species, posing a challenge for both theirmeasurement in laboratory studies and their inclusion in air quality andclimate models. Mass spectrometry techniques can measure thousands of thesespecies, giving insight into these chemical processes, but the datasetsthemselves are highly complex. Data reduction techniques that groupcompounds in a chemically and kinetically meaningful way provide a route tosimplify the chemistry of these systems but have not been systematicallyinvestigated. Here we evaluate three approaches to reducing thedimensionality of oxidation systems measured in an environmental chamber:positive matrix factorization (PMF), hierarchical clustering analysismore »
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Validation of satellite formaldehyde (HCHO) retrievals using observations from 12 aircraft campaignsAbstract. Formaldehyde (HCHO) has been measured from space for morethan 2 decades. Owing to its short atmospheric lifetime, satellite HCHOdata are used widely as a proxy of volatile organic compounds (VOCs; pleaserefer to Appendix A for abbreviations and acronyms), providing constraintson underlying emissions and chemistry. However, satellite HCHO products fromdifferent satellite sensors using different algorithms have received littlevalidation so far. The accuracy and consistency of HCHO retrievals remainlargely unclear. Here we develop a validation platform for satellite HCHOretrievals using in situ observations from 12 aircraft campaigns with a chemicaltransport model (GEOS-Chem) as the intercomparison method. Application tothe NASA operational OMImore »