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Creators/Authors contains: "Frasso, Michael A."

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  1. A high-temperature retro-Diels–Alder reaction is accelerated by microwave (MW) heating to rates higher than expected based on Arrhenius kinetics and the measured temperature of the reaction mixture. Observations are consistent with selective MW heating of the polar reactant relative to other, less polar components of the reaction mixture.
  2. After some initial false-starts, the international synthetic organic community is slowing warming to the possibility of certain strategic advantages of microwave heating in chemical synthesis.