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Abstract Kepler-51 is a ≲1 Gyr old Sun-like star hosting three transiting planets with radii ≈6–9R_⊕and orbital periods ≈45–130 days. Transit timing variations (TTVs) measured with past Kepler and Hubble Space Telescope (HST) observations have been successfully modeled by considering gravitational interactions between the three transiting planets, yielding low masses and low mean densities (≲0.1 g cm⁻³) for all three planets. However, the transit time of the outermost transiting planet Kepler-51d recently measured by the James Webb Space Telescope 10 yr after the Kepler observations is significantly discrepant from the prediction made by the three-planet TTV model, which we confirmed with ground-based and follow-up HST observations. We show that the departure from the three-planet model is explained by including a fourth outer planet, Kepler-51e, in the TTV model. A wide range of masses (≲M_Jup) and orbital periods (≲10 yr) are possible for Kepler-51e. Nevertheless, all the coplanar solutions found from our brute-force search imply masses ≲10M_⊕for the inner transiting planets. Thus, their densities remain low, though with larger uncertainties than previously estimated. Unlike other possible solutions, the one in which Kepler-51e is around the 2:1 mean motion resonance with Kepler-51d implies low orbital eccentricities (≲0.05) and comparable masses (∼5M_⊕) for all four planets, as is seen in other compact multiplanet systems. This work demonstrates the importance of long-term follow-up of TTV systems for probing longer-period planets in a system. 

Abstract Carbon dioxide (CO₂) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO₂is an indicator of the metal enrichment (that is, elements heavier than helium, also called ‘metallicity’)^1–3, and thus the formation processes of the primary atmospheres of hot gas giants^4–6. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets^7–9. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO₂, but have not yielded definitive detections owing to the lack of unambiguous spectroscopic identification^10–12. Here we present the detection of CO₂in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science programme^13,14. The data used in this study span 3.0–5.5 micrometres in wavelength and show a prominent CO₂absorption feature at 4.3 micrometres (26-sigma significance). The overall spectrum is well matched by one-dimensional, ten-times solar metallicity models that assume radiative–convective–thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide and hydrogen sulfide in addition to CO₂, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 micrometres that is not reproduced by these models.