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Creators/Authors contains: "Gall, Elliott T."

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  1. We quantify volatile organic compound (VOC) emissions from indoor surface swabs and portable air cleaner (PAC) filters collected in a home thirty days after the 2025 Los Angeles wildland-urban interface (WUI) fires. We calculate emissions for seventeen fire-relevant compounds. Surface emissions exceeded those of clean controls, and emissions from a windowsill in a room without a PAC were ~15× and ~2× higher for benzene and toluene, respectively, than rates reported in the literature for comparable materials unaffected by smoke/soot. Particle filters in PACs installed at the start of the fire emitted aromatics at rates comparable to those reported in a study where filters operated for 200 days in a city; emissions from activated carbon filters exceeded by >10× those of the particle filter. A windowsill in a room without a PAC off-gassed more VOC mass than a windowsill in a room with a PAC, suggesting that air cleaners can reduce surface contamination. Modeling with benzene emission rates from impacted surfaces in a hypothetical indoor space resulted in a predicted indoor concentration ~6× greater than outdoors. This study shows surfaces act as persistent VOC sources following WUI fires and indicates indoor surfaces affect exposure during and after fire events. 
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  2. Building insulation materials can affect indoor air by (i) releasing primary volatile organic compounds (VOCs) from building enclosure cavities to the interior space, (ii) mitigating exposure to outdoor pollutants through reactive deposition (of oxidants, e.g. , ozone) or filtration (of particles) in infiltration air, and (iii) generating secondary VOCs and other gas-phase byproducts resulting from oxidant reactions. This study reports primary VOC emission fluxes, ozone (O 3 ) reaction probabilities ( γ ), and O 3 reaction byproduct yields for eight common, commercially available insulation materials. Fluxes of primary VOCs from the materials, measured in a continuous flow reactor using proton transfer reaction-time of flight-mass spectrometry, ranged from 3 (polystyrene with thermal backing) to 61 (cellulose) μmol m −2 h −1 (with total VOC mass emission rates estimated to be between ∼0.3 and ∼3.3 mg m −2 h −1 ). Major primary VOC fluxes from cellulose were tentatively identified as compounds likely associated with cellulose chemical and thermal decomposition products. Ozone-material γ ranged from ∼1 × 10 −6 to ∼30 × 10 −6 . Polystyrene with thermal backing and polyisocyanurate had the lowest γ , while cellulose and fiberglass had the highest. In the presence of O 3 , total observed volatile byproduct yields ranged from 0.25 (polystyrene) to 0.85 (recycled denim) moles of VOCs produced per mole of O 3 consumed, or equivalent to secondary fluxes that range from 0.71 (polystyrene) to 10 (recycled denim) μmol m −2 h −1 . Major emitted products in the presence of O 3 were generally different from primary emissions and were characterized by yields of aldehydes and acetone. This work provides new data that can be used to evaluate and eventually model the impact of “hidden” materials ( i.e. , those present inside wall cavities) on indoor air quality. The data may also guide building enclosure material selection, especially for buildings in areas of high outdoor O 3 . 
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